C₂₇H₄₇NO₃Si

Base Information

Chemical Name:C₂₇H₄₇NO₃Si
CAS No.:1266245-97-9
Molecular Formula:C₂₇H₄₇NO₃Si
Molecular Weight:461.761
Hs Code.:

C<sub>27</sub>H<sub>47</sub>NO<sub>3</sub>Si

Synonyms:C₂₇H₄₇NO₃Si

Suppliers and Price of C₂₇H₄₇NO₃Si

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₂₇H₄₇NO₃Si

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₂₇H₄₇NO₃Si

There total 11 articles about C₂₇H₄₇NO₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1319713-25-1
C₃₃H₄₉NO₄SSi

: 1266245-97-9
C₂₇H₄₇NO₃Si

Guidance literature:: With disodium hydrogenphosphate; sodium amalgam; In tetrahydrofuran; at 20 ℃; Inert atmosphere;
DOI:10.1016/j.tetlet.2011.05.091

Reference yield:

: 1319713-15-9
C₁₀H₁₃BrO₄

: 1266245-97-9
C₂₇H₄₇NO₃Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: triethylamine / dichloromethane / 24 h / 20 °C / Inert atmosphere; Reflux

2.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 1.17 h / -78 - 20 °C / Inert atmosphere

3.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

3.2: 2 h / Inert atmosphere

4.1: palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / Inert atmosphere; Reflux

5.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.83 h / 0 °C / Inert atmosphere

6.1: triethylamine / dichloromethane / 24 h / 20 °C / Inert atmosphere; Reflux

7.1: sodium tetrahydroborate / tetrahydrofuran; methanol / 0.5 h / 0 - 20 °C / Inert atmosphere

7.2: 1 h / Inert atmosphere; Reflux

8.1: dihydrogen peroxide / water / 1 h / 0 - 20 °C / Inert atmosphere

9.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

9.2: 3 h / -60 °C / Inert atmosphere

10.1: sodium amalgam; disodium hydrogenphosphate / tetrahydrofuran / 20 °C / Inert atmosphere

With sodium tetrahydroborate; disodium hydrogenphosphate; sodium amalgam; lithium aluminium tetrahydride; oxalyl dichloride; dihydrogen peroxide; palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; dimethyl sulfoxide; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; water; toluene; 2.1: Swern oxidation / 3.1: Horner-Wadsworth-Emmons olefination;
DOI:10.1016/j.tetlet.2011.05.091

Reference yield:

: 1319713-16-0
C₁₉H₃₃BrO₄Si

: 1266245-97-9
C₂₇H₄₇NO₃Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 1.17 h / -78 - 20 °C / Inert atmosphere

2.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

2.2: 2 h / Inert atmosphere

3.1: palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / Inert atmosphere; Reflux

4.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.83 h / 0 °C / Inert atmosphere

5.1: triethylamine / dichloromethane / 24 h / 20 °C / Inert atmosphere; Reflux

6.1: sodium tetrahydroborate / tetrahydrofuran; methanol / 0.5 h / 0 - 20 °C / Inert atmosphere

6.2: 1 h / Inert atmosphere; Reflux

7.1: dihydrogen peroxide / water / 1 h / 0 - 20 °C / Inert atmosphere

8.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

8.2: 3 h / -60 °C / Inert atmosphere

9.1: sodium amalgam; disodium hydrogenphosphate / tetrahydrofuran / 20 °C / Inert atmosphere

With sodium tetrahydroborate; disodium hydrogenphosphate; sodium amalgam; lithium aluminium tetrahydride; oxalyl dichloride; dihydrogen peroxide; palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; dimethyl sulfoxide; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; water; toluene; 1.1: Swern oxidation / 2.1: Horner-Wadsworth-Emmons olefination;
DOI:10.1016/j.tetlet.2011.05.091