[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*2CH₃OH=[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*2CH₃OH

Base Information

• Chemical Name: [Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*2CH₃OH=[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*2CH₃OH
• CAS No.: 96616-78-3
• Molecular Formula: BF₄*2CH₄O*C₄₅H₄₉N₂P₂Rh₂
• Molecular Weight: 1036.54

Synonyms:[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*2CH₃OH=[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*2CH₃OH

Chemical Property of [Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*2CH₃OH=[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*2CH₃OH

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Technology Process of [Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*2CH₃OH=[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*2CH₃OH

There total 2 articles about [Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*2CH₃OH=[Rh₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*2CH₃OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate + [Ni2[C3HN2(CH2P(C6H5)2)2]2](2+)*2ClO4(1-)*2CH3CN=[Ni2[C3HN2(CH2P(C6H5)2)2]2](ClO4)2*2CH3CN (96633-02-2) → [Rh2(C8H12)2(C3HN2(CH2P(C6H5)2)2)](1+)*BF4(1-)*2CH3OH=[Rh2(C8H12)2(C3HN2(CH2P(C6H5)2)2)]BF4*2CH3OH (96616-78-3)

Guidance literature:

With sodium cyanide; triethylamine; In dichloromethane; water; benzene; under N2 or Ar, reflux of Ni-complex and NaCN in benzene and H2O, sepn.of the org. layer containing the free pyrazole ligand, addn. of this dried soln. to Rh-complex in CH2Cl2, then addn. of Et3N; removal of solvents under vac., filtn. of dissoluted in hot MeOH oily residue, slow cooling of soln., filtn., crystals washed and dried, elem. anal.;

Reference yield:

bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (35138-22-8) + [Ir(3,5-bis((diphenylphosphino)methyl)pyrazole)(cod)]2(BF4)2 → [(cod)Rh(3,5-bis((diphenylphosphino)methyl)pyrazolato)Rh(cod)]BF4 (96616-78-3) + [(cod)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Rh(cod)]BF4 (881493-81-8) + [(cod)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(cod)]BF4 (96532-20-6)

Guidance literature:

With triethylamine; In dichloromethane; 1.) (Ir(cod)2)BF4; 2.) Et3N;

DOI:10.1021/om050896m

Reference yield: 100.0%

[Rh2(C8H12)2(C3HN2(CH2P(C6H5)2)2)](1+)*BF4(1-)*2CH3OH=[Rh2(C8H12)2(C3HN2(CH2P(C6H5)2)2)]BF4*2CH3OH (96616-78-3) → [Rh2(CO)4(C3HN2(CH2P(C6H5)2)2)](1+)*BF4(1-)*0.25CH2Cl2=[Rh2(CO)4(C3HN2(CH2P(C6H5)2)2)]BF4*0.25CH2Cl2 (96633-00-0)

Guidance literature:

With carbon monoxide; In dichloromethane; byproducts: 1,5-cyclooctadiene; soln. of complex is treated with CO, further work-up under CO; addn. of hexane, recrystn. of ppt. from CH2Cl2/hexane, elem. anal.;

upstream raw materials:

[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN

bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Downstream raw materials:

[Rh₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Rh₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂

[Rh₂(P(C₆H₅)2)(CO)2(C₃HN₂(CH₂P(C₆H₅)2)2)]

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