C₄₁H₄₇F₃O₁₀SSi

Base Information

Chemical Name:C₄₁H₄₇F₃O₁₀SSi
CAS No.:392663-65-9
Molecular Formula:C₄₁H₄₇F₃O₁₀SSi
Molecular Weight:816.965
Hs Code.:

C<sub>41</sub>H<sub>47</sub>F<sub>3</sub>O<sub>10</sub>SSi

Synonyms:C₄₁H₄₇F₃O₁₀SSi

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₄₁H₄₇F₃O₁₀SSi

Chemical Property:

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Technology Process of C₄₁H₄₇F₃O₁₀SSi

There total 23 articles about C₄₁H₄₇F₃O₁₀SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 157240-43-2
(4R)-4,5-isopropylidenedioxy-1-(dimethoxyphosphoryl)-2-pentanone

: 392663-65-9
C₄₁H₄₇F₃O₁₀SSi

Guidance literature:: Multi-step reaction with 23 steps

1: 86 percent / LiCl; iPr₂NEt / acetonitrile / 12 h / 25 °C

2: 98 percent / LiAlH₄; LiI / diethyl ether / 0.5 h / -100 °C

3: 97 percent / AcOH; H₂O / 5 h / 25 °C

4: 70 percent / N-iodosuccinimide; NaHCO₃ / tetrahydrofuran / 2.5 h / 0 °C

5: 90 percent / Et₃N; 4-DMAP / CH₂Cl₂ / 3 h / -10 - 0 °C

6: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -10 °C

7: 99 percent / H₂ / Raney Ni / ethanol / 1 h / 25 °C

8: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

9: 99 percent / Dess Martin periodinane / CH₂Cl₂ / 2 h / 25 °C

10: 87 percent / tetrahydrofuran / 3 h / -78 - -10 °C

11: 95 percent / Dess Martin periodinane / CH₂Cl₂ / 3 h / 25 °C

12: 98 percent / triethyl orthoformate; pTsOH / 55 °C

13: OsO₄; H₂O; N-methylmorpholine / 2-methyl-propan-2-ol; tetrahydrofuran / 14 h / 25 °C

14: NaIO₄; H₂O / 5 h / 25 °C / pH 7

15: 87 percent / nBuLi / hexane; tetrahydrofuran / 0.67 h / -20 °C

16: 88 percent / Dess Martin periodinane / CH₂Cl₂ / 1 h / 25 °C

17: 85 percent / TMSOTf / CH₂Cl₂ / 1 h / -78 - -30 °C

18: 93 percent / pyridine / 2 h / 25 °C

19: 91 percent / NBS; 2,6-lutidine / acetonitrile; H₂O / 2 h / 25 °C

20: 92 percent / NaBH₄ / methanol / 0.08 h / -5 °C

21: 56 percent / TFA / CH₂Cl₂ / 4 h / 25 °C

22: 80 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 1 h / -78 °C

23: 83 percent / KHMDS / toluene; tetrahydrofuran / 0.75 h / -78 °C

With 4-methyl-morpholine; pyridine; 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; sodium periodate; N-Bromosuccinimide; N-iodo-succinimide; osmium(VIII) oxide; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; trimethylsilyl trifluoromethanesulfonate; water; hydrogen; potassium hexamethylsilazane; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; orthoformic acid triethyl ester; trifluoroacetic acid; lithium chloride; lithium iodide; palladium dihydroxide; nickel; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 9: Dess-Martin oxidation / 11: Dess-Martin oxidation / 16: Dess-Martin oxidation / 22: Swern oxidation;
DOI:10.1002/1521-3773(20011105)40

Reference yield:

: 392663-03-5
(E)-(2R,4S,7S)-8-Benzyloxy-7-methyl-oct-5-ene-1,2,4-triol

: 392663-65-9
C₄₁H₄₇F₃O₁₀SSi

Guidance literature:: Multi-step reaction with 20 steps

1: 70 percent / N-iodosuccinimide; NaHCO₃ / tetrahydrofuran / 2.5 h / 0 °C

2: 90 percent / Et₃N; 4-DMAP / CH₂Cl₂ / 3 h / -10 - 0 °C

3: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -10 °C

4: 99 percent / H₂ / Raney Ni / ethanol / 1 h / 25 °C

5: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

6: 99 percent / Dess Martin periodinane / CH₂Cl₂ / 2 h / 25 °C

7: 87 percent / tetrahydrofuran / 3 h / -78 - -10 °C

8: 95 percent / Dess Martin periodinane / CH₂Cl₂ / 3 h / 25 °C

9: 98 percent / triethyl orthoformate; pTsOH / 55 °C

10: OsO₄; H₂O; N-methylmorpholine / 2-methyl-propan-2-ol; tetrahydrofuran / 14 h / 25 °C

11: NaIO₄; H₂O / 5 h / 25 °C / pH 7

12: 87 percent / nBuLi / hexane; tetrahydrofuran / 0.67 h / -20 °C

13: 88 percent / Dess Martin periodinane / CH₂Cl₂ / 1 h / 25 °C

14: 85 percent / TMSOTf / CH₂Cl₂ / 1 h / -78 - -30 °C

15: 93 percent / pyridine / 2 h / 25 °C

16: 91 percent / NBS; 2,6-lutidine / acetonitrile; H₂O / 2 h / 25 °C

17: 92 percent / NaBH₄ / methanol / 0.08 h / -5 °C

18: 56 percent / TFA / CH₂Cl₂ / 4 h / 25 °C

19: 80 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 1 h / -78 °C

20: 83 percent / KHMDS / toluene; tetrahydrofuran / 0.75 h / -78 °C

With 4-methyl-morpholine; pyridine; 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; sodium periodate; N-Bromosuccinimide; N-iodo-succinimide; osmium(VIII) oxide; n-butyllithium; oxalyl dichloride; trimethylsilyl trifluoromethanesulfonate; water; hydrogen; potassium hexamethylsilazane; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; orthoformic acid triethyl ester; trifluoroacetic acid; palladium dihydroxide; nickel; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 6: Dess-Martin oxidation / 8: Dess-Martin oxidation / 13: Dess-Martin oxidation / 19: Swern oxidation;
DOI:10.1002/1521-3773(20011105)40

Reference yield:

: 392663-00-2
(E)-(S)-6-Benzyloxy-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-methyl-hex-3-en-2-one

: 392663-65-9
C₄₁H₄₇F₃O₁₀SSi

Guidance literature:: Multi-step reaction with 22 steps

1: 98 percent / LiAlH₄; LiI / diethyl ether / 0.5 h / -100 °C

2: 97 percent / AcOH; H₂O / 5 h / 25 °C

3: 70 percent / N-iodosuccinimide; NaHCO₃ / tetrahydrofuran / 2.5 h / 0 °C

4: 90 percent / Et₃N; 4-DMAP / CH₂Cl₂ / 3 h / -10 - 0 °C

5: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -10 °C

6: 99 percent / H₂ / Raney Ni / ethanol / 1 h / 25 °C

7: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

8: 99 percent / Dess Martin periodinane / CH₂Cl₂ / 2 h / 25 °C

9: 87 percent / tetrahydrofuran / 3 h / -78 - -10 °C

10: 95 percent / Dess Martin periodinane / CH₂Cl₂ / 3 h / 25 °C

11: 98 percent / triethyl orthoformate; pTsOH / 55 °C

12: OsO₄; H₂O; N-methylmorpholine / 2-methyl-propan-2-ol; tetrahydrofuran / 14 h / 25 °C

13: NaIO₄; H₂O / 5 h / 25 °C / pH 7

14: 87 percent / nBuLi / hexane; tetrahydrofuran / 0.67 h / -20 °C

15: 88 percent / Dess Martin periodinane / CH₂Cl₂ / 1 h / 25 °C

16: 85 percent / TMSOTf / CH₂Cl₂ / 1 h / -78 - -30 °C

17: 93 percent / pyridine / 2 h / 25 °C

18: 91 percent / NBS; 2,6-lutidine / acetonitrile; H₂O / 2 h / 25 °C

19: 92 percent / NaBH₄ / methanol / 0.08 h / -5 °C

20: 56 percent / TFA / CH₂Cl₂ / 4 h / 25 °C

21: 80 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 1 h / -78 °C

22: 83 percent / KHMDS / toluene; tetrahydrofuran / 0.75 h / -78 °C

With 4-methyl-morpholine; pyridine; 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; sodium periodate; N-Bromosuccinimide; N-iodo-succinimide; osmium(VIII) oxide; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; trimethylsilyl trifluoromethanesulfonate; water; hydrogen; potassium hexamethylsilazane; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; dimethyl sulfoxide; triethylamine; orthoformic acid triethyl ester; trifluoroacetic acid; lithium iodide; palladium dihydroxide; nickel; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 8: Dess-Martin oxidation / 10: Dess-Martin oxidation / 15: Dess-Martin oxidation / 21: Swern oxidation;
DOI:10.1002/1521-3773(20011105)40