Technology Process of C25H35NO4S
There total 1 articles about C25H35NO4S which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 2 steps
1.1: 76 percent / NaH / tetrahydrofuran; various solvent(s); dimethylformamide / 16 h / 20 °C
2.1: Mg; 1,2-dibromoethane / tetrahydrofuran / 20 °C
2.2: CuBr*SMe2; LiCl / tetrahydrofuran / -78 °C
2.3: 90 percent / trimethylsilyl chloride / tetrahydrofuran / 1.5 h
With
sodium hydride; magnesium; ethylene dibromide;
In
tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/anie.200603353
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: 89 percent / DIBAL-H / CH2Cl2 / 2 h
2.1: Et3N; (cyclohexyl)2BOTf / CH2Cl2; hexane / 2.33 h
2.2: 86 percent / CH2Cl2 / 14 h / cooling
3.1: 17.1 mmol / NaH / various solvent(s) / 0.42 h
4.1: 75 percent / 2,6-lutidine / CH2Cl2 / 0.58 h
5.1: 98 percent / ceric ammonium nitrate / acetonitrile; H2O / 1 h
6.1: 86 percent / 2,6-lutidine / CH2Cl2 / 0.5 h
7.1: 59 percent / diisobutylaluminium hydride / CH2Cl2 / -78 - 20 °C
8.1: 80 percent / Dess-Martin periodinane; NaHCO3 / CH2Cl2 / 1 h / 20 °C
9.1: 94 percent / LDA / hexane; tetrahydrofuran / 0.25 h / cooling
With
2,6-dimethylpyridine; ammonium cerium(IV) nitrate; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; lithium diisopropyl amide;
In
tetrahydrofuran; hexane; dichloromethane; water; acetonitrile;
DOI:10.1002/anie.200603353
