[(N,N'dicyclohexylethanediimine)FeCl₂]

Base Information

• Chemical Name: [(N,N'dicyclohexylethanediimine)FeCl₂]
• CAS No.: 110551-83-2
• Molecular Formula: C₁₄H₂₄Cl₂FeN₂
• Molecular Weight: 347.111
• Mol file: 110551-83-2.mol

Synonyms:[(N,N'dicyclohexylethanediimine)FeCl₂]

Chemical Property of [(N,N'dicyclohexylethanediimine)FeCl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(N,N'dicyclohexylethanediimine)FeCl₂]

There total 8 articles about [(N,N'dicyclohexylethanediimine)FeCl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

N,N'-di-cyclohexyl-1,4-diazabuta-1,3-diene + iron(II) chloride → [(N,N'dicyclohexylethanediimine)FeCl2] (110551-83-2)

Guidance literature:

In dichloromethane; (N2), Schlenk techniques; dissolving N compd. and FeCl2 in CH2Cl2, stirring overinght; evapn. under vacuum, washing with hexane, addn. of CH2Cl2, filtration, evapn. under vacuum, elem. anal.;

DOI:10.1039/c0dt01614d

Reference yield:

(iron(III))(trichloride)(N2C2H2)(cyclohexyl)2 (474396-91-3) → [(N,N'dicyclohexylethanediimine)FeCl2] (110551-83-2)

Guidance literature:

With (C₆H₅)CH₂MgCl; In not given; byproducts: C6H5CH2CH2C6H5; -78°C;

DOI:10.1002/anie.200502985

Reference yield:

N,N'-di-cyclohexyl-1,4-diazabuta-1,3-diene → [(N,N'dicyclohexylethanediimine)FeCl2] (110551-83-2)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: (C₆H₅)CH₂MgCl / not given

With (C₆H₅)CH₂MgCl; In dichloromethane;

DOI:10.1002/anie.200502985

upstream raw materials:

cis-[Fe(CO)4Cl₂]

bis[glyoxalbis(cyclohexylimine)]iron

nitrosylchloride

(iron(III))(trichloride)(N₂C₂H₂)(cyclohexyl)2

Downstream raw materials:

[1,4-dicyclohexyl-1,4-diazabuta-1,3-diene]Fe(iodide)2

[1,4-dicyclohexyl-1,4-diazabuta-1,3-diene]Fe(iodide)2(carbonyl)2

Refernces

• 1、 Child, Chloe R.,Kealey, Steven,Jones, Harriet,Miller, Philip W.,White, Andrew J. P.,Gee, Anthony D.,Long, Nicholas J.. "Binding and photodissociation of CO in iron(ii) complexes for application in positron emission tomography (PET) radiolabelling". . p. 6210 - 6215. Retrieved 2011/08/02.
• 2、 Shaver, Michael P.,Allan, Laura E. N.,Rzepa, Henry S.,Gibson, Vernon C.. "Correlation of metal spin state with catalytic reactivity: Polymerizations mediated by α-diimine-iron complexes". . p. 1241 - 1244. Retrieved 2007/10/03.