Br(CH₃)2C₆H₂NCHC₆H₄O^(1-)*Tl⁽¹⁺⁾=Br(CH₃)2C₆H₂NCHC₆H₄OTl

Base Information

• Chemical Name: Br(CH₃)2C₆H₂NCHC₆H₄O^(1-)*Tl⁽¹⁺⁾=Br(CH₃)2C₆H₂NCHC₆H₄OTl
• CAS No.: 432050-10-7
• Molecular Formula: C₁₅H₁₃BrNOTl
• Molecular Weight: 507.561
• Mol file: 432050-10-7.mol

Synonyms:Br(CH₃)2C₆H₂NCHC₆H₄O^(1-)*Tl⁽¹⁺⁾=Br(CH₃)2C₆H₂NCHC₆H₄OTl

Chemical Property of Br(CH₃)2C₆H₂NCHC₆H₄O^(1-)*Tl⁽¹⁺⁾=Br(CH₃)2C₆H₂NCHC₆H₄OTl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Br(CH₃)2C₆H₂NCHC₆H₄O^(1-)*Tl⁽¹⁺⁾=Br(CH₃)2C₆H₂NCHC₆H₄OTl

There total 1 articles about Br(CH₃)2C₆H₂NCHC₆H₄O^(1-)*Tl⁽¹⁺⁾=Br(CH₃)2C₆H₂NCHC₆H₄OTl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N-(4-bromo-2,6-dimethylphenyl)-2-hydroxy-1-phenylmethaneimine + thallium (I) ethoxide (20398-06-5) → Br(CH3)2C6H2NCHC6H4O(1-)*Tl(1+)=Br(CH3)2C6H2NCHC6H4OTl (432050-10-7)

Guidance literature:

In tetrahydrofuran; (Ar), mixed dropwise at room temp., stirred at room temp. for 2 h; filtered (N2);

DOI:10.1016/S1381-1169(01)00451-4

Reference yield: 81.0%

Br(CH3)2C6H2NCHC6H4O(1-)*Tl(1+)=Br(CH3)2C6H2NCHC6H4OTl (432050-10-7) + Cl2Ru[=C=C(H)SiMe3](PCy3)2 → (CH3)2BrC6H2NCHC6H4ORuClP(C6H11)3CCHSi(CH3)3

Guidance literature:

In tetrahydrofuran; byproducts: TlCl; (Ar), ligand in THF treated with Ru complex in THF, stirred at room temp. for 4 h; filtered, recrystd.(pentane, -70°C), elem. anal.;

DOI:10.1016/S1381-1169(03)00099-2

Reference yield:

Br(CH3)2C6H2NCHC6H4O(1-)*Tl(1+)=Br(CH3)2C6H2NCHC6H4OTl (432050-10-7) + [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) → [(C7H5NO)Ru(Cl)(C6H4(CH3)(CH(CH3)2))(C6H2(CH3)2Br)] (406911-92-0)

Guidance literature:

In tetrahydrofuran; byproducts: TlCl; (Ar), mixed, stirred at room temp. for 6 h; filtered, evapd., crystd.(toluene) at 0°C, washed (cold toluene),dried, elem. anal., IR, NMR;

DOI:10.1016/S1381-1169(01)00451-4

upstream raw materials:

thallium (I) ethoxide

Downstream raw materials:

[(C₇H₅NO)Ru(Cl)(C₆H₄(CH₃)(CH(CH₃)2))(C₆H₂(CH₃)2Br)]