METHYL 3-(BENZYLOXY)-4-BROMOBENZOATE 98

Base Information

• Chemical Name: METHYL 3-(BENZYLOXY)-4-BROMOBENZOATE 98
• CAS No.: 17054-26-1
• Molecular Formula: C15H13 Br O3
• Molecular Weight: 321.17
• Hs Code.: 2918990090
• Mol file: 17054-26-1.mol

Synonyms:Benzoicacid, 3-(benzyloxy)-4-bromo-, methyl ester (8CI)

Chemical Property of METHYL 3-(BENZYLOXY)-4-BROMOBENZOATE 98

Chemical Property:

• Vapor Pressure: 3.15E-07mmHg at 25°C
• Melting Point: 81-83
• Boiling Point: 419°Cat760mmHg
• Flash Point: 207.2°C
• PSA: 35.53000
• Density: 1.407g/cm³
• LogP: 3.81470
• Storage Temp.: Keep Cold

Purity/Quality:

98% ^*data from raw suppliers

Methyl 3-(benzyloxy)-4-bromobenzoate 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL 3-(BENZYLOXY)-4-BROMOBENZOATE 98

There total 1 articles about METHYL 3-(BENZYLOXY)-4-BROMOBENZOATE 98 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ methyl 3-(benzyloxy)-4-bromobenzoate (17054-26-1)

Guidance literature:

4-Brom-3-hydroxy-benzoesaeuremethylester, Benzylchlorid, A., K2CO3, Δ;

Reference yield: 95.0%

4-fluoroboronic acid (1765-93-1) + methyl 3-(benzyloxy)-4-bromobenzoate (17054-26-1) → methyl 2-(benzyloxy)-4'-fluorobiphenyl-4-carboxylate

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium carbonate; In water; toluene; at 100 ℃;

DOI:10.1016/j.bmc.2017.06.003

Reference yield:

1-ethenyl-2-pyrrolidinone (88-12-0) + methyl 3-(benzyloxy)-4-bromobenzoate (17054-26-1) → methyl 3-(benzyloxy)-4-(1-(2-oxopyrrolidin-1-yl)vinyl)benzoate

Guidance literature:

With N-Methyldicyclohexylamine; palladium diacetate; XPhos; In 1,4-dioxane; at 100 ℃; for 18h; Inert atmosphere;