C₅₉H₉₇ClO₁₃Si

Base Information

Chemical Name:C₅₉H₉₇ClO₁₃Si
CAS No.:1293966-80-9
Molecular Formula:C₅₉H₉₇ClO₁₃Si
Molecular Weight:1077.95
Hs Code.:

C<sub>59</sub>H<sub>97</sub>ClO<sub>13</sub>Si

Synonyms:C₅₉H₉₇ClO₁₃Si

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Chemical Property of C₅₉H₉₇ClO₁₃Si

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Technology Process of C₅₉H₉₇ClO₁₃Si

There total 45 articles about C₅₉H₉₇ClO₁₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1293966-65-0
C₂₅H₄₂O₅Si

: 1293966-76-3
C₃₄H₅₇ClO₉

: 1293966-80-9
C₅₉H₉₇ClO₁₃Si

Guidance literature:: With dmap; camphor-10-sulfonic acid; dicyclohexyl-carbodiimide; In dichloromethane; at 30 ℃; for 15h;
DOI:10.1021/ol2007296

Reference yield:

: 1293966-33-2
C₁₉H₂₄O₅S

: 1293966-80-9
C₅₉H₉₇ClO₁₃Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: samarium diiodide / tetrahydrofuran; methanol / 0.5 h / -10 °C / Inert atmosphere

2.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

3.1: potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 0 °C / Inert atmosphere

4.1: 1H-imidazole; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

5.1: pyridine / acetonitrile / 0.5 h / 0 °C / Inert atmosphere

6.1: water; potassium acetate / acetonitrile / 12 h / 0 °C / Inert atmosphere

7.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / Inert atmosphere

7.2: 2 h / -78 °C / Inert atmosphere

8.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

9.1: dmap; camphor-10-sulfonic acid; dicyclohexyl-carbodiimide / dichloromethane / 15 h / 30 °C

With pyridine; 1H-imidazole; dmap; samarium diiodide; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; water; tert.-butyl lithium; potassium acetate; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetonitrile; pentane; 2.1: Mitsunobu reaction / 5.1: Pummerer rearrangement;
DOI:10.1021/ol2007296

Reference yield:

: 1293966-31-0
(4S,5S)-2,2-dimethyl-4-((S)-oxiran-2-yl)-5-vinyl-1,3-dioxolane

: 1293966-80-9
C₅₉H₉₇ClO₁₃Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -20 °C / Inert atmosphere

1.2: 1 h / -20 °C / Inert atmosphere

2.1: ethylmagnesium bromide; lithium chloride / tetrahydrofuran; diethyl ether / 24 h / 20 °C / Inert atmosphere

3.1: water; calcium carbonate; methyl iodide / acetonitrile / 15 h / 40 °C / Inert atmosphere

4.1: samarium diiodide / tetrahydrofuran; methanol / 0.5 h / -10 °C / Inert atmosphere

5.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

6.1: potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 0 °C / Inert atmosphere

7.1: 1H-imidazole; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

8.1: pyridine / acetonitrile / 0.5 h / 0 °C / Inert atmosphere

9.1: water; potassium acetate / acetonitrile / 12 h / 0 °C / Inert atmosphere

10.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / Inert atmosphere

10.2: 2 h / -78 °C / Inert atmosphere

11.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

12.1: dmap; camphor-10-sulfonic acid; dicyclohexyl-carbodiimide / dichloromethane / 15 h / 30 °C

With pyridine; 1H-imidazole; dmap; n-butyllithium; samarium diiodide; camphor-10-sulfonic acid; ethylmagnesium bromide; tetrabutyl ammonium fluoride; water; tert.-butyl lithium; potassium acetate; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; calcium carbonate; lithium chloride; diethylazodicarboxylate; methyl iodide; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; acetonitrile; pentane; 5.1: Mitsunobu reaction / 8.1: Pummerer rearrangement;
DOI:10.1021/ol2007296