[(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)]

Base Information

• Chemical Name: [(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)]
• CAS No.: 1187643-58-8
• Molecular Formula: C₃₄H₄₂Cl₂IrP
• Molecular Weight: 744.807
• Mol file: 1187643-58-8.mol

Synonyms:[(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)]

Chemical Property of [(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)]

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of [(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)]

There total 1 articles about [(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + 2,6-dimesitylphenylphosphine → [(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)] (1187643-58-8)

Guidance literature:

In dichloromethane; (N2) mixt. Ir complex and phosphine in CH2Cl2 was stirred at room temp. for 30 min; soln. was evapd. to dryness, residue was cromd. on silica (CHCl3 followed by CHCl3-Et2O 4:1) and crystd. from CH2Cl2-pentane at -20°C;

DOI:10.1021/ja9048509

Reference yield: 64.0%

[(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)] (1187643-58-8) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [(η5-Cp*)(2,6-xylylisocyanide)IrP(2,6-dimesitylphenyl)C=N-2,6-dimethylphenyl]

Guidance literature:

With 1,8-diazabicyclo-[5.4.0]undec-7-ene; In dichloromethane; (N2) soln. Ir complex in CH2Cl2 was added to mixt. 2,6-xylyl isocyanide and DBU in CH2Cl2 at -78°C, allowed to warm to room temp.; soln. was evapd. to dryness, residue was washed with pentane and extd. into Et2O, soln. was filtered, concd. and cooled to -20°C;

DOI:10.1021/ja9048509

Reference yield:

[(η5-Cp*)IrCl2(PH2-2,6-dimesitylphenyl)] (1187643-58-8) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [(η5-Cp*)(2,6-xylyl isocyanide)Ir=P(2,6-dimesitylphenyl)]

Guidance literature:

With 1,8-diazabicyclo-[5.4.0]undec-7-ene; In dichloromethane; toluene; (N2) to soiln. Ir complex in CH2Cl2 soln. 2,6-xylylisocyanide and DBU were added at room temp., stirred at room temp. for 3 h; identified by NMR;

DOI:10.1021/ja9048509

upstream raw materials:

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]