methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

Base Information

Chemical Name:methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside
CAS No.:253596-67-7
Molecular Formula:C₄₁H₅₀O₁₁
Molecular Weight:718.841
Hs Code.:

Synonyms:methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

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Chemical Property of methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

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Technology Process of methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

There total 3 articles about methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 253596-66-6
methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-heptopyranos-6-ulose-7(E)-ylidene]-α-D-glucopyranoside

: 253596-67-7
methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

: (E)-(S)-1-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-Tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-yl)-3-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-prop-2-en-1-ol

Guidance literature:: With zinc borohydride; In diethyl ether; at 0 ℃; for 0.5h;
DOI:10.1080/07328309908544046

Reference yield:

: 83051-88-1
methyl 6-aldehydo-2,3,4-tri-O-benzyl-α-D-glucopyranoside

: 253596-67-7
methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / potassium carbonate; 18-crown-6 / toluene / 20 °C

2: 64 percent / zinc borohydride / diethyl ether / 0.5 h / 0 °C

With 18-crown-6 ether; zinc borohydride; potassium carbonate; In diethyl ether; toluene; 1: Substitution / 2: Reduction;
DOI:10.1080/07328309908544046

Reference yield:

: 150591-92-7
dimethyl (1,2:3,4-di-O-isopropylidene-α-D-galacto-heptopyranos-6-ulos-7-yl)phosphonate

: 253596-67-7
methyl 2,3,4-tri-O-benzyl-6-deoxy-6-C-[7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7(E)-ylidene]-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / potassium carbonate; 18-crown-6 / toluene / 20 °C

2: 64 percent / zinc borohydride / diethyl ether / 0.5 h / 0 °C

With 18-crown-6 ether; zinc borohydride; potassium carbonate; In diethyl ether; toluene; 1: Substitution / 2: Reduction;
DOI:10.1080/07328309908544046