(+)-lactiflorin

Base Information

Chemical Name:(+)-lactiflorin
CAS No.:1361049-59-3
Molecular Formula:C₂₃H₂₆O₁₀
Molecular Weight:462.453
Hs Code.:

Synonyms:(+)-lactiflorin

Suppliers and Price of (+)-lactiflorin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 12 raw suppliers

Chemical Property of (+)-lactiflorin

Chemical Property:

Boiling Point:677.3±55.0 °C(Predicted)
Density:1.56±0.1 g/cm3(Predicted)

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (+)-lactiflorin

There total 20 articles about (+)-lactiflorin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1361049-68-4
C₄₄H₄₄O₁₀

: 1361049-59-3
(+)-lactiflorin

Guidance literature:: With 20 wt.% Pd(OH)2 on activated carbon; hydrogen; In ethanol; at 20 ℃; for 4h; under 760.051 Torr;
DOI:10.1002/anie.201106889

Reference yield:

: 1361049-72-0
(5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(methoxycarbonyl)furan-2(5H)-one

: 1361049-59-3
(+)-lactiflorin

Guidance literature:: Multi-step reaction with 11 steps

1.1: barium hydroxide octahydrate / tetrahydrofuran; water / 60 h / 20 °C

2.1: 4-methyl-morpholine; methyl chloroformate / tetrahydrofuran / 0.5 h / -10 °C

2.2: 0.5 h / 0 °C

3.1: dmap; triethylamine / dichloromethane / 1.5 h / 0 - 20 °C

4.1: acetone; acetonitrile / 2 h / Irradiation

4.2: 16 h / 20 °C / 760.05 Torr

5.1: t-butyldimethylsiyl triflate / hexane; dichloromethane / 12 h / 0 °C / Molecular sieve

6.1: tetrahydrofuran; diethyl ether / -78 °C

7.1: pyridinium p-toluenesulfonate / dichloromethane / 3 h / 20 °C

8.1: dmap; triethylamine / 18 h / 20 °C

9.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C

10.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 4 h / 20 °C

11.1: 20 wt.% Pd(OH)2 on activated carbon; hydrogen / ethanol / 4 h / 20 °C / 760.05 Torr

With 4-methyl-morpholine; dmap; barium hydroxide octahydrate; 20 wt.% Pd(OH)2 on activated carbon; t-butyldimethylsiyl triflate; tetrabutyl ammonium fluoride; hydrogen; pyridinium p-toluenesulfonate; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; methyl chloroformate; In tetrahydrofuran; diethyl ether; ethanol; hexane; dichloromethane; water; acetone; acetonitrile;
DOI:10.1002/anie.201106889

Reference yield:

: 1361049-71-9
C₁₆H₂₆O₆Si

: 1361049-59-3
(+)-lactiflorin

Guidance literature:: Multi-step reaction with 12 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 - 20 °C

1.2: 21 h / 20 °C

2.1: barium hydroxide octahydrate / tetrahydrofuran; water / 60 h / 20 °C

3.1: 4-methyl-morpholine; methyl chloroformate / tetrahydrofuran / 0.5 h / -10 °C

3.2: 0.5 h / 0 °C

4.1: dmap; triethylamine / dichloromethane / 1.5 h / 0 - 20 °C

5.1: acetone; acetonitrile / 2 h / Irradiation

5.2: 16 h / 20 °C / 760.05 Torr

6.1: t-butyldimethylsiyl triflate / hexane; dichloromethane / 12 h / 0 °C / Molecular sieve

7.1: tetrahydrofuran; diethyl ether / -78 °C

8.1: pyridinium p-toluenesulfonate / dichloromethane / 3 h / 20 °C

9.1: dmap; triethylamine / 18 h / 20 °C

10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C

11.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 4 h / 20 °C

12.1: 20 wt.% Pd(OH)2 on activated carbon; hydrogen / ethanol / 4 h / 20 °C / 760.05 Torr

With 4-methyl-morpholine; dmap; barium hydroxide octahydrate; 20 wt.% Pd(OH)2 on activated carbon; t-butyldimethylsiyl triflate; tetrabutyl ammonium fluoride; hydrogen; pyridinium p-toluenesulfonate; sodium hydride; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; methyl chloroformate; In tetrahydrofuran; diethyl ether; ethanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; mineral oil;
DOI:10.1002/anie.201106889