[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl)

Base Information

• Chemical Name: [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl)
• CAS No.: 691888-02-5
• Molecular Formula: C₄₈H₇₄N₃Sc
• Molecular Weight: 738.092
• Mol file: 691888-02-5.mol

Synonyms:[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl)

Chemical Property of [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl)

There total 3 articles about [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

[(2,6-(i-Pr)2C6H3NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C6H3)ScCl2] (241165-09-3) + 2,6-diisopropylbenzenamine (24544-04-5) + methyllithium (917-54-4) → [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl) (691888-02-5)

Guidance literature:

[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]; methyllithium; In toluene; at -78 - 20 ℃;

2,6-diisopropylbenzenamine; In toluene; at 20 ℃; for 12h;

DOI:10.1021/om300913d

Reference yield: 47.0%

[(((CH3)2CH)2C6H3NC(C(CH3)3)CHC(C(CH3)3)NC6H3(CH(CH3)2)2)ScCl(NHC6H3(CH(CH3)2)2)] (691888-00-3) + methyllithium (917-54-4) → [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl) (691888-02-5)

Guidance literature:

In toluene; byproducts: LiCl; (Ar); Schlenk technique; toluene was condensed into Sc complex and MeLi;mixt. was stirred at 35°C for 24 h; solvent removed (vac.); hexane added; mixt. warmed to 40°C; filtered; extd. (hexane); solvent removed (vac.); recrystd. (hexane, -36°C); elem. anal.;

DOI:10.1021/om034345c

Reference yield:

[(2,6-(i-Pr)2C6H3NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C6H3)ScCl2] (241165-09-3) + lithium (2,6-diisopropylphenyl)amide → [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl) (691888-02-5)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: toluene

In toluene;

DOI:10.1021/om034345c

upstream raw materials:

[(((CH₃)2CH)2C₆H₃NC(C(CH₃)3)CHC(C(CH₃)3)NC₆H₃(CH(CH₃)2)2)ScCl(NHC₆H₃(CH(CH₃)2)2)]

methyllithium

[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

2,6-diisopropylbenzenamine

Downstream raw materials:

C₅₁H₈₁N₄Sc

C₅₁H₇₉⁽²⁾H₂N₄Sc

C₅₅H₇₆N₃Sc

C₅₄H₈₀N₅Sc