Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate

Base Information

• Chemical Name: Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate
• CAS No.: 83400-91-3
• Molecular Formula: C6H9O4K
• Molecular Weight: 184.23
• Mol file: 83400-91-3.mol

Synonyms:1,3-Dioxolane-4-carboxylicacid, 2,2-dimethyl-, potassium salt (7CI,9CI);2,2-Dimethyl-1,3-dioxolane-4-carboxylicacid potassium salt;2,3-O-Isopropylideneglyceric acid potassium salt;Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate;

Chemical Property of Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate

Chemical Property:

• PSA: 58.59000
• LogP: -1.11220
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

Potassium2,2-Dimethyl-1,3-dioxolane-4-carboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate

There total 4 articles about Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol (100-79-8,36543-79-0) → 2,2-dimethyl-1,3-dioxolane-4-carboxylic acid potassium salt (83400-91-3)

Guidance literature:

With potassium permanganate; potassium hydroxide; In water; at 0 - 20 ℃;

Reference yield:

2,3-isopropylidene-glyceraldehyde (15186-48-8) → 2,2-dimethyl-1,3-dioxolane-4-carboxylic acid potassium salt (83400-91-3)

Guidance literature:

With potassium hydroxide; potassium permanganate; In water; at 20 - 23 ℃; for 1.5h;

Reference yield:

O1,O2;O5,O6-diisopropylidene-mannitol (82188-74-7) → 2,2-dimethyl-1,3-dioxolane-4-carboxylic acid potassium salt (83400-91-3)

Guidance literature:

With potassium permanganate; sodium periodate; Product distribution / selectivity;

upstream raw materials:

2,3-isopropylidene-glyceraldehyde

1,2:5,6-di-O-isopropylidene-D-mannitol

O¹,O²;O⁵,O⁶-diisopropylidene-mannitol

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

Downstream raw materials:

N-(O-Isopropyliden-D-glyceroyl)-L-phenylalanin-tert-butylester

N-(O-Isopropyliden-D-glyceroyl)-(S-benzyl)-L-cysteinmethylester

N-(O-Isopropyliden-D-glyceroyl)-(S-benzyl)-L-cystein

N-(O-Isopropyliden-D-glyceroyl)-L-phenylalaninmethylester