(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

Base Information

Chemical Name:(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate
CAS No.:1338809-86-1
Molecular Formula:C₃₂H₂₉O₁₇P
Molecular Weight:716.546
Hs Code.:

Synonyms:(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

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Chemical Property of (2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

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Technology Process of (2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

There total 7 articles about (2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1338810-03-9
(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(dibenzyloxyphosphoryloxy)benzoate

: 1338809-86-1
(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

Guidance literature:: With 20% palladium hydroxide on charcoal; hydrogen; In ethyl acetate; at 20 ℃; for 4h;
DOI:10.1016/j.tetlet.2011.08.061

Reference yield:

: 1338809-99-6
(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(methoxymethoxy)benzoate

: 1338809-86-1
(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: trimethylsilyl bromide / dichloromethane / 4 h / 0 - 20 °C

2: tetrachloromethane; dmap; N-ethyl-N,N-diisopropylamine / acetonitrile / 2 h

3: 20% palladium hydroxide on charcoal; hydrogen / ethyl acetate / 4 h / 20 °C

With tetrachloromethane; dmap; trimethylsilyl bromide; 20% palladium hydroxide on charcoal; hydrogen; N-ethyl-N,N-diisopropylamine; In dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1016/j.tetlet.2011.08.061

Reference yield:

: 1338810-01-7
(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(hydroxy)benzoate

: 1338809-86-1
(2R,3R)-5,7-diacetoxy-2-(3,4,5-triacetoxyphenyl)-chroman-3-yl 4-(phosphoryloxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: tetrachloromethane; dmap; N-ethyl-N,N-diisopropylamine / acetonitrile / 2 h

2: 20% palladium hydroxide on charcoal; hydrogen / ethyl acetate / 4 h / 20 °C

With tetrachloromethane; dmap; 20% palladium hydroxide on charcoal; hydrogen; N-ethyl-N,N-diisopropylamine; In ethyl acetate; acetonitrile;
DOI:10.1016/j.tetlet.2011.08.061