((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)

Base Information

Chemical Name:((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)
CAS No.:106419-01-6
Molecular Formula:C₁₇H₃₁FeP
Molecular Weight:322.254
Hs Code.:

((CH<sub>2</sub>C(CH<sub>3</sub>))2CH)2Fe(P(CH<sub>3</sub>)3)

Synonyms:((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)

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Chemical Property of ((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)

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Technology Process of ((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)

There total 1 articles about ((CH₂C(CH₃))2CH)2Fe(P(CH₃)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 74205-98-4
potassium 2,4-dimethylpentadienide-tetrahydrofuran

: iron(II) chloride

: 594-09-2
trimethylphosphane

: 1000-86-8
2,4-Dimethyl-1,3-pentadiene

: 106419-02-7
(CH₂C(CH₃)CHC(CH₂)2)Fe(P(CH₃)3)3

: 106419-01-6
((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)

Guidance literature:: In tetrahydrofuran; FeCl2(1.5 equiv.) and PMe3(3 equiv.) refluxed in THF for 1 h under inert atm., cooled to -78°C, K(1+)-2,4.Me2pd(1-)(2.0 equiv.) in THF added over 30 min, stirred for 15 min at -78°C and for 2 h at room temp.; filtered through Celite, evapd., extd. with pentane, crystd. at -30°C: yield of crude product 48%; elem. anal.;
DOI:10.1021/om00146a009

Reference yield: 74.0%

: 106419-01-6
((CH₂C(CH₃))2CH)2Fe(P(CH₃)3)

: 1493-13-6
trifluorormethanesulfonic acid

: 594-09-2
trimethylphosphane

: 1000-86-8
2,4-Dimethyl-1,3-pentadiene

: 106419-07-2
{HP(CH₃)3}⁽¹⁺⁾*CF₃SO₃^(1-) = {HP(CH₃)3}CF₃SO₃

: 106419-06-1
((CH₂C(CH₃))2CH)Fe(P(CH₃)3)3⁽¹⁺⁾*O₃SCF₃^(1-)=((CH₂C(CH₃))2CH)Fe(P(CH₃)3)3O₃SCF₃

Guidance literature:: In diethyl ether; CF3SO3H in Et2O added dropwise over 10 min to cold (-78°C), stirred soln. of Fe complex in Et2O under inert atm., stirred at -78°C for 10 min, PMe3 in Et2O added, stirred at -78°C for 45 min, allowed to warm to room temp.; mixt. of Fe complex and phosphine salt in 63:37 molar ratio pptd., detected by NMR, attempts to separate the two components were unsuccessful, elem. anal.; diene analyzed by GC;
DOI:10.1021/om00146a009