tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

Base Information

Chemical Name:tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane
CAS No.:1466415-25-7
Molecular Formula:C₄₆H₇₂O₆Si₂
Molecular Weight:777.245
Hs Code.:

tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

Synonyms:tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

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Chemical Property of tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

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Technology Process of tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

There total 1 articles about tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: tert-butyl(2-((2S,4S/R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)-4-iodotetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

: 1466415-25-7
tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

Guidance literature:: With palladium 10% on activated carbon; hydrogen; sodium hydrogencarbonate; In methanol; ethyl acetate; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1002/chem.201301796

Reference yield: 80.0%

: 1466415-25-7
tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

: 1466415-26-8
(3R,5S)-5-(tert-butyldimethylsilyloxy)-6-((2S,6R)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)tetrahydro-2H-pyran-2-yl)-3-methoxy-6-methylheptan-1-ol

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 0 ℃; for 0.833333h;
DOI:10.1002/chem.201301796

Reference yield:

: 1466415-25-7
tert-butyl(2-((2R,6S)-6-((3S,5R)-3-(tert-butyldimethylsilyloxy)-5-methoxy-7-(4-methoxybenzyloxy)-2-methylheptan-2-yl)tetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

: 1466415-27-9
(3S,5S)-5-(tert-butyldimethylsilyloxy)-6-((2S,6R)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)tetrahydro-2H-pyran-2-yl)-3-methoxy-6-methylheptanal

Guidance literature:: Multi-step reaction with 2 steps

1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0.83 h / 0 °C

2: Dess-Martin periodane / dichloromethane / 4 h / 0 °C

With Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1002/chem.201301796