3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone

Base Information

• Chemical Name: 3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone
• CAS No.: 1110631-89-4
• Molecular Formula: C₂₉H₂₆O₇
• Molecular Weight: 486.521
• Mol file: 1110631-89-4.mol

Synonyms:3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone

Chemical Property of 3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone

There total 1 articles about 3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4’-(benzyloxy)-4-bromo-3,6-dimethoxy-[1,1’-biphenyl]-2,5-dione (1110631-68-9) + 3,4-Dimethoxyphenylboronic acid (122775-35-3) → 3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone (1110631-89-4)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride; In toluene; at 70 ℃; for 10h;

DOI:10.1021/ol802645f

Reference yield: 80.0%

3-(3,4-dimethoxyphenyl)-2,5-dimethoxy-6-(4-benzyloxyphenyl)-1,4-benzoquinone (1110631-89-4) → 3-(3,4-Dihydroxyphenyl)-2,5-dihydroxy-6-(4-hydroxyphenyl)-1,4-benzochinon (Leucomelon) (479-63-0)

Guidance literature:

With boron tribromide; In dichloromethane; at -78 - 20 ℃; for 8h;

DOI:10.1021/ol802645f

upstream raw materials:

4’-(benzyloxy)-4-bromo-3,6-dimethoxy-[1,1’-biphenyl]-2,5-dione

3,4-Dimethoxyphenylboronic acid

Downstream raw materials:

3-(3,4-Dihydroxyphenyl)-2,5-dihydroxy-6-(4-hydroxyphenyl)-1,4-benzochinon (Leucomelon)