bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate

Base Information

• Chemical Name: bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate
• CAS No.: 871362-15-1
• Molecular Formula: CF₃O₃S*C₁₄H₈F₆I
• Molecular Weight: 566.183
• Mol file: 871362-15-1.mol

Synonyms:bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate

Chemical Property of bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate

There total 5 articles about bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

trifluorormethanesulfonic acid (1493-13-6) + 4-Iodobenzotrifluoride (455-13-0) + 4-trifluoromethylphenylboronic acid (128796-39-4) → bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate (871362-15-1)

Guidance literature:

4-Iodobenzotrifluoride; With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 1h;

4-trifluoromethylphenylboronic acid; In dichloromethane; at 0 - 20 ℃; for 1.25h;

trifluorormethanesulfonic acid; In dichloromethane; at 0 ℃; for 0.0833333h;

DOI:10.1021/acs.organomet.5b00350

Reference yield: 56.0%

4-Iodobenzotrifluoride (455-13-0) + 4-trifluoromethylphenylboronic acid (128796-39-4) → bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate (871362-15-1)

Guidance literature:

4-Iodobenzotrifluoride; With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 1h;

4-trifluoromethylphenylboronic acid; In dichloromethane; at 20 ℃; for 0.25h;

DOI:10.1021/acs.orglett.5b01079

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + (4-(trifluoromethyl)phenyl)-λ3-iodanediyl diacetate (69180-48-9) + 4-trifluoromethylphenylboronic acid (128796-39-4) → bis(4-(trifluoromethyl)phenyl)iodonium trifluoromethanesulfonate (871362-15-1)

Guidance literature:

4-trifluoromethylphenylboronic acid; With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.166667h;

(4-(trifluoromethyl)phenyl)-λ³-iodanediyl diacetate; In dichloromethane; at 20 ℃; for 1.5h;

trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 0.333333h;

DOI:10.1039/c5cc04944j

upstream raw materials:

trifluorormethanesulfonic acid

4-Iodobenzotrifluoride

4-trifluoromethylphenylboronic acid

(4-(trifluoromethyl)phenyl)-λ³-iodanediyl diacetate

Downstream raw materials:

(S)-2-(4-(trifluoromethyl)phenyl)-1-octanol

(S)-3-(2-(4-(trifluoromethyl)phenyl)propanoyl)oxazolidin-2-one

(3aS,8aR)-1-benzyl-8-methyl-3a-(4-(trifluoromethyl)phenyl)-3,3a,8,8atetrahydropyrrolo[2,3-b]indol-2(1H)-one

1-methyl-2-(4-(trifluoromethyl)phenyl)-1H-pyrrole