Fe(H)2(η-H2)(PPh2Et)3

Base Information

Chemical Name:Fe(H)2(η-H2)(PPh2Et)3
CAS No.:102149-40-6
Molecular Formula:C₄₂H₄₉FeP₃
Molecular Weight:702.619
Hs Code.:

Synonyms:Fe(H)2(η-H2)(PPh2Et)3

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Chemical Property of Fe(H)2(η-H2)(PPh2Et)3

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Technology Process of Fe(H)2(η-H2)(PPh2Et)3

There total 2 articles about Fe(H)2(η-H2)(PPh2Et)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 132233-13-7
(P(C₆H₅)2C₂H₅)3FeH₃Cu(P(C₆H₅)2C₂H₅)

: 102149-40-6
Fe(H)2(η-H2)(PPh2Et)3

Guidance literature:: With triflic acid; In benzene-d6; a benzene-d6 soln. of the Fe-Cu-complex is reacted with either 1 equiv or an excess of triflic acid under Ar or H2 at 0°C; NMR-spectra of the soln.;

Reference yield:

: 16940-66-2
sodium tetrahydroborate

: 607-01-2
ethyl-diphenyl-phosphane

: iron(II) chloride

: 102149-40-6
cis,mer-Fe(H)2(η2-H2)(PEtPh2)3

Guidance literature:: With hydrogen; In ethanol; H2 atmosphere; addn. of PEtPh2 to soln. of FeCl2 in EtOH, cooling (ice-bath), addn. of NaBH4 (over 30 min), bubbling with H2 (room temp., 7 h); filtration off, washing (EtOH). extn. (toluene), layer (EtOH, -20°C, few days), removal of mother liquor, drying (stream of H2);

Reference yield: 90.0%

: 102149-40-6
Fe(H)2(η-H2)(PPh2Et)3

: 132233-16-0
2Cu⁽¹⁺⁾*2(OC₄H₉)^(1-)*2{P(C₆H₅)2(C₂H₅)} = {Cu(OC₄H₉)(P(C₆H₅)2C₂H₅)}2

: 132233-13-7
(P(C₆H₅)2C₂H₅)3FeH₃Cu(P(C₆H₅)2C₂H₅)

Guidance literature:: In hexane; the Fe-complex is partially dissolved in hexane under H2 and the Cu-complex is added with stirring at 0°C, after removal of the ice bath and stirring for 2 h the slurry is placed in a freezer at -40°C; filtn. of the ppt., recrystn. through gentle warming of a hexane soln., filtn. of insoluble material, cooling to room temp. and slow evapn. of the solvent, elem. anal.;