IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C)

Base Information

• Chemical Name: IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C)
• CAS No.: 1159444-93-5
• Molecular Formula: C₂₄H₂₄ClF₃IrN
• Molecular Weight: 611.129
• Mol file: 1159444-93-5.mol

Synonyms:IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C)

Chemical Property of IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C)

Chemical Property:

Purity/Quality:

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Technology Process of IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C)

There total 1 articles about IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + N-(4-(trifluoromethyl)benzylidene)aniline (79128-83-9) → IrCl(η5-C5Me5)(N-(4-(trifluoromethyl)benzylidene)aniline(1-)-κN,C) (1159444-93-5)

Guidance literature:

With sodium acetate; In dichloromethane; under N2; mixt. of Ir compd. (0.063 mmol), NaOAc (0.39 mmol), aniline deriv. (0.13 mmol), and aldehyde (traces) in CH2Cl2 stirred at room temp. overnight; mixt. filtered through Celite, filtrate evapd. to dryness, solid washed with hexane; elem. anal.;

DOI:10.1021/om9000742

upstream raw materials:

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

N-(4-(trifluoromethyl)benzylidene)aniline

Refernces