2,6-Decahydronaphthalenediol

Base Information

• Chemical Name: 2,6-Decahydronaphthalenediol
• CAS No.: 102942-69-8
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.252
• Mol file: 102942-69-8.mol

Synonyms:2,6-DECAHYDRONAPHTHALENEDIOL

Chemical Property of 2,6-Decahydronaphthalenediol

Chemical Property:

• PSA: 40.46000
• LogP: 1.30840

Purity/Quality:

98%min ^*data from raw suppliers

2,6-DECAHYDRONAPHTHALENEDIOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,6-Decahydronaphthalenediol

There total 12 articles about 2,6-Decahydronaphthalenediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-hydroxy-6-methoxy-1,2,3,4-tetrahydronaphthalene (1447-87-6) → (+/-)-(4ar,8at)-decahydro-naphthalene-2c,6c-diol (36667-87-5,36667-88-6,36667-89-7,37089-52-4,37089-53-5,37089-57-9,37089-58-0,102942-69-8,111407-18-2)

Guidance literature:

Multi-step reaction with 4 steps

1: lithium; liquid NH₃; diethyl ether / und anschliessend mit Oxalsaeure

2: ethanolic HCl

3: Reduktion mit Lithium in fluessigem NH₃ und anschliessendes Hydrolyse mit wss.-methanol.HCl

4: NaBH₄

With hydrogenchloride; sodium tetrahydroborate; diethyl ether; ammonia; lithium;

DOI:10.1021/ja01530a047

Reference yield:

(+/-)-6-hydroxy-3,4,5,6,7,8-hexahydro-1H-naphthalen-2-one (103385-78-0) → (+/-)-(4ar,8at)-decahydro-naphthalene-2c,6c-diol (36667-87-5,36667-88-6,36667-89-7,37089-52-4,37089-53-5,37089-57-9,37089-58-0,102942-69-8,111407-18-2)

Guidance literature:

Multi-step reaction with 3 steps

1: ethanolic HCl

2: Reduktion mit Lithium in fluessigem NH₃ und anschliessendes Hydrolyse mit wss.-methanol.HCl

3: NaBH₄

With hydrogenchloride; sodium tetrahydroborate;

DOI:10.1021/ja01530a047

Reference yield:

(+/-)-6c-hydroxy-(4ar)-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one (40429-97-8,40429-99-0) → (+/-)-(4ar,8at)-decahydro-naphthalene-2c,6c-diol (36667-87-5,36667-88-6,36667-89-7,37089-52-4,37089-53-5,37089-57-9,37089-58-0,102942-69-8,111407-18-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Reduktion mit Lithium in fluessigem NH₃ und anschliessendes Hydrolyse mit wss.-methanol.HCl

2: NaBH₄

With sodium tetrahydroborate;

DOI:10.1021/ja01530a047

upstream raw materials:

cis-bicyclo<4.4.0>decane-3,8-dione

(+/-)-6c-hydroxy-(4ar,8ac)-octahydro-naphthalen-2-one

2-hydroxy-6-methoxy-1,2,3,4-tetrahydronaphthalene

(+/-)-6-hydroxy-3,4,5,6,7,8-hexahydro-1H-naphthalen-2-one

Refernces