4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone

Base Information

• Chemical Name: 4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone
• CAS No.: 188014-49-5
• Molecular Formula: C₁₃H₁₁NS₂Se
• Molecular Weight: 324.329
• Mol file: 188014-49-5.mol

Synonyms:4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone

Chemical Property of 4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone

There total 2 articles about 4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Trifluoro-methanesulfonate4,6-dimethyl-2-methylsulfanyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrol-1-ylium; → 4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone (188014-49-5)

Guidance literature:

With sodium hydrogen selenide; In ethanol; for 1h;

DOI:10.1021/jo962303a

Reference yield:

4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-thione (183479-97-2) → 4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone (188014-49-5)

Guidance literature:

Multi-step reaction with 2 steps

1: CH₂Cl₂ / 4 h / Ambient temperature

2: 75 percent / NaSeH / ethanol / 1 h

With sodium hydrogen selenide; In ethanol; dichloromethane;

DOI:10.1021/jo962303a

Reference yield:

4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-selone (188014-49-5) → 2-(5,6-Dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-4,6-dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole

Guidance literature:

Multi-step reaction with 2 steps

1: CH₂Cl₂ / 4 h / Ambient temperature

2: 43 percent / Et₃N / acetonitrile / 1 h / Ambient temperature

With triethylamine; In dichloromethane; acetonitrile;

DOI:10.1021/jo962303a

upstream raw materials:

4,6-Dimethyl-5-phenyl-5H-[1,3]dithiolo[4,5-c]pyrrole-2-thione