O⁴,O⁶-((R)-benzylidene)-D-glucose oxime

Base Information

• Chemical Name: O⁴,O⁶-((R)-benzylidene)-D-glucose oxime
• CAS No.: 105929-91-7
• Molecular Formula: C₁₃H₁₇NO₆
• Molecular Weight: 283.281
• Mol file: 105929-91-7.mol

Synonyms:O⁴,O⁶-((R)-benzylidene)-D-glucose oxime

Chemical Property of O⁴,O⁶-((R)-benzylidene)-D-glucose oxime

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of O⁴,O⁶-((R)-benzylidene)-D-glucose oxime

There total 1 articles about O⁴,O⁶-((R)-benzylidene)-D-glucose oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2R,3R)-2,3-Dihydroxy-3-((2R,4R,5R)-5-hydroxy-2-phenyl-[1,3]dioxan-4-yl)-propionaldehyde (83212-64-0) → O4,O6-((R)-benzylidene)-D-glucose oxime (105929-91-7)

Guidance literature:

With ethanol; hydroxylamine;

DOI:10.1021/ja01236a031

Reference yield: 98.0%

O4,O6-((R)-benzylidene)-D-glucose oxime (105929-91-7) + 4-nitrobenzaldehdye (555-16-8) → 4,6-O-Benzyliden-N-(p-nitrobenzyliden)-β-D-glucopyranosylamin-N-oxid (105874-59-7)

Guidance literature:

toluene-4-sulfonic acid; In dimethyl sulfoxide; Ambient temperature;

DOI:10.1002/hlca.19860690526

Reference yield:

O4,O6-((R)-benzylidene)-D-glucose oxime (105929-91-7) + acetic anhydride (108-24-7) → O2,O3,O5-triacetyl-O4,O6-((R)-benzylidene)-D-glucononitrile

Guidance literature:

With sodium acetate; at 120 ℃;

DOI:10.1021/ja01236a031

upstream raw materials:

(2R,3R)-2,3-Dihydroxy-3-((2R,4R,5R)-5-hydroxy-2-phenyl-[1,3]dioxan-4-yl)-propionaldehyde

Downstream raw materials:

4,6-O-Benzyliden-N-(p-nitrobenzyliden)-β-D-glucopyranosylamin-N-oxid

1-deoxy-1-nitro-4,6-O-benzylidene-β-D-glucose