1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

Base Information

Chemical Name:1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane
CAS No.:132981-30-7
Molecular Formula:C₁₆H₁₉NO₃S
Molecular Weight:305.398
Hs Code.:

Synonyms:1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

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Chemical Property of 1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

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Technology Process of 1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

There total 5 articles about 1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 132981-29-4
3-<<(o-isothiocyanatobenzoyl)oxy>methyl>-3-tert-butyloxetane

: 132981-30-7
1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: With boron trifluoride diethyl etherate; Ambient temperature;
DOI:10.1021/jm00109a002

Reference yield:

: 99250-47-2
3-t-butyl-3-hydroxymethyl-oxetane

: 132981-30-7
1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / pyridine / CH₂Cl₂ / 12 h / Ambient temperature

2: 80 percent / H₂ / 10percent Pd/C / ethyl acetate / 0.67 h / 2585.7 Torr

3: 74 percent / aq. NaHCO₃ / CHCl₃ / 0.33 h / Ambient temperature

4: 39 percent / BF₃*Et₂O / Ambient temperature

With pyridine; boron trifluoride diethyl etherate; hydrogen; sodium hydrogencarbonate; palladium on activated charcoal; In dichloromethane; chloroform; ethyl acetate;
DOI:10.1021/jm00109a002

Reference yield:

: 132981-28-3
3-<<(o-nitrobenzoyl)oxy>methyl>-3-tert-butyloxetane

: 132981-30-7
1-(o-isothiocyanatophenyl)-4-tert-butyl-2,6,7-trioxabicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / H₂ / 10percent Pd/C / ethyl acetate / 0.67 h / 2585.7 Torr

2: 74 percent / aq. NaHCO₃ / CHCl₃ / 0.33 h / Ambient temperature

3: 39 percent / BF₃*Et₂O / Ambient temperature

With boron trifluoride diethyl etherate; hydrogen; sodium hydrogencarbonate; palladium on activated charcoal; In chloroform; ethyl acetate;
DOI:10.1021/jm00109a002