7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

Base Information

Chemical Name:7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside
CAS No.:865179-82-4
Molecular Formula:C₂₉H₄₄N₂O₁₆S
Molecular Weight:708.738
Hs Code.:

Synonyms:7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

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Chemical Property of 7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

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Technology Process of 7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

There total 8 articles about 7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 32564-25-3
bis(4-nitrophenyl)adipate

: 385842-67-1
3-(2-aminoethylthio)propyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

: 865179-82-4
7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

Guidance literature:: In N,N-dimethyl-formamide; for 5h;
DOI:10.1021/jo051065t

Reference yield:

: 865179-71-1
allyl (3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

: 865179-82-4
7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: DMSO; Ac₂O / 18 h / 20 °C

2: 1.32 g / L-Selectride / tetrahydrofuran / -78 - 20 °C

3: methanol; CH₂Cl₂ / UV-irradiation

4: Na; NH₃ / 2-methyl-propan-2-ol; tetrahydrofuran

5: 64 percent / dimethylformamide / 5 h

With ammonia; sodium; acetic anhydride; L-Selectride; dimethyl sulfoxide; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/jo051065t

Reference yield:

: 865179-70-0
allyl (3,4,6-tri-O-benzyl-2-O-acetyl-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

: 865179-82-4
7-aza-8,13-dioxo-13-(4-nitrophenoxy)-4-thiatridecanyl (β-D-mannopyranosyl)-(1->2)-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / NaOMe / methanol / 20 °C

2: DMSO; Ac₂O / 18 h / 20 °C

3: 1.32 g / L-Selectride / tetrahydrofuran / -78 - 20 °C

4: methanol; CH₂Cl₂ / UV-irradiation

5: Na; NH₃ / 2-methyl-propan-2-ol; tetrahydrofuran

6: 64 percent / dimethylformamide / 5 h

With ammonia; sodium methylate; sodium; acetic anhydride; L-Selectride; dimethyl sulfoxide; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/jo051065t