methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Base Information

Chemical Name:methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside
CAS No.:81099-74-3
Molecular Formula:C₂₄H₃₂O₄
Molecular Weight:384.516
Hs Code.:

Synonyms:methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Suppliers and Price of methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

There total 21 articles about methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 85271-59-6
methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucohept-6-enopyranoside

: 81099-74-3
methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Guidance literature:: With lithium aluminium tetrahydride;
DOI:10.1016/S0040-4039(01)82945-2

Reference yield:

: 81099-75-4
1,6-anhydro-3-O-benzyl-2-desoxy-2,4-di-C-methyl-β-D-glucopyranose

: 81099-74-3
methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 96 percent / NaH / dimethylformamide / 1.5 h

2: 59 percent / HCl / 2 h / 20 °C

3: 83 percent / DMSO, (COCl)2 / CH₂Cl₂ / 0.42 h / -60 °C

4: 90 percent / n-BuLi / hexane; benzene / 1.) 15 min, 2.) reflux, 20 min

5: 80 percent / LiAlH₄, CoCl₂ / tetrahydrofuran / 0.08 h / -40 °C

With hydrogenchloride; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; sodium hydride; dimethyl sulfoxide; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1007/BF01142802

Reference yield:

: 81076-85-9
methyl-2-desoxy-2,4-di-C-methyl-3,4-di-O-benzyl-6-aldo-α-D-glucopyranoside

: 81099-74-3
methyl-2,6,7-tridesoxy-2,4-di-C-methyl-3,4-di-O-benzyl-α-D-glucoheptapyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / n-BuLi / hexane; benzene / 1.) 15 min, 2.) reflux, 20 min

2: 80 percent / LiAlH₄, CoCl₂ / tetrahydrofuran / 0.08 h / -40 °C

With lithium aluminium tetrahydride; n-butyllithium; In tetrahydrofuran; hexane; benzene;
DOI:10.1007/BF01142802