methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Base Information

• Chemical Name: methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside
• CAS No.: 129870-10-6
• Molecular Formula: C₄₁H₄₀O₁₅
• Molecular Weight: 772.76
• Mol file: 129870-10-6.mol

Synonyms:methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Chemical Property of methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside

There total 4 articles about methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C62H58O15 (1192366-15-6) → methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside (129870-10-6)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethyl acetate; for 48h; under 3000.2 Torr; Yield given;

DOI:10.1016/0008-6215(90)80057-A

Reference yield:

methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside (34212-64-1,641635-63-4) → methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside (129870-10-6)

Guidance literature:

Multi-step reaction with 2 steps

1: AgOTf, molecular sieves / CH₂Cl₂ / 0 deg C to r.t.

2: H₂ / 10percent Pd/C / ethyl acetate / 48 h / 3000.2 Torr

With molecular sieve; hydrogen; silver trifluoromethanesulfonate; palladium on activated charcoal; In dichloromethane; ethyl acetate;

DOI:10.1016/0008-6215(90)80057-A

Reference yield:

2,3,4,6-tetra-O-Bz-α-D-mannopyranosyl bromide (127305-34-4) → methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside (129870-10-6)

Guidance literature:

Multi-step reaction with 2 steps

1: AgOTf, molecular sieves / CH₂Cl₂ / 0 deg C to r.t.

2: H₂ / 10percent Pd/C / ethyl acetate / 48 h / 3000.2 Torr

With molecular sieve; hydrogen; silver trifluoromethanesulfonate; palladium on activated charcoal; In dichloromethane; ethyl acetate;

DOI:10.1016/0008-6215(90)80057-A

upstream raw materials:

2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide

methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside

C₆₂H₅₈O₁₅

2,3,4,6-tetra-O-Bz-α-D-mannopyranosyl bromide

Downstream raw materials:

methyl 2,4-di-O-acetyl-6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside

methyl 2,4-di-O-acetyl-6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-D-mannopyranosyl)-α-D-mannopyranoside