(C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)]

Base Information

• Chemical Name: (C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)]
• CAS No.: 201595-93-9
• Molecular Formula: C₈H₂₀N*C₂₄H₁₅NO₅PSW
• Molecular Weight: 774.53

Synonyms:(C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)]

Chemical Property of (C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)]

Chemical Property:

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Technology Process of (C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)]

There total 1 articles about (C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

W(CO)5(PPh2H) (18399-62-7) + tetraethylammonium bromide (71-91-0) + phenyl isothiocyanate (103-72-0) → (C2H5)4N(1+)*(CO)5W(P(C6H5)2C(S)NC6H5)(1-)=[(C2H5)4N][(CO)5W(P(C6H5)2C(S)NC6H5)] (201595-93-9)

Guidance literature:

With n-BuLi; In methanol; diethyl ether; N2-atmosphere; stirring (0°C to room temp., 5 min), PhNCS addn., stirring (10 min), pptn. on Et4NBr soln. (MeOH) addn.; filtering, washing (hexane), drying (vac.); elem. anal.;

DOI:10.1021/om970418e

Reference yield: 68.0%

(C2H5)4N(1+)*(CO)5W(P(C6H5)2C(S)NC6H5)(1-)=[(C2H5)4N][(CO)5W(P(C6H5)2C(S)NC6H5)] (201595-93-9) → [Et4N][W(CO)4(η(2)-PPh2C(=NPh)S)] (201595-95-1)

Guidance literature:

In benzene; Irradiation (UV/VIS); N2-atmosphere; irradn. (UV, room temp., 5 min); evapn. (vac.), crystn. (CH2Cl2 / hexane = 1 / 2, -20°C, 12 h); elem. anal.;

DOI:10.1021/om970418e

Reference yield:

(C2H5)4N(1+)*(CO)5W(P(C6H5)2C(S)NC6H5)(1-)=[(C2H5)4N][(CO)5W(P(C6H5)2C(S)NC6H5)] (201595-93-9) → (CO)5W(P(C6H5)2C(NC6H5)SCH2CCH) (201595-96-2)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: acetonitrile

In acetonitrile; benzene;

DOI:10.1021/om970418e

upstream raw materials:

W(CO)5(PPh2H)

tetraethylammonium bromide

phenyl isothiocyanate

Downstream raw materials:

[Et4N][W(CO)4(η(2)-PPh2C(=NPh)S)]

(CO)5W(P(C₆H₅)2C(NC₆H₅)SCH₂CHCH₂)

(CO)5W(P(C₆H₅)2C(NC₆H₅)SCH₂CN)

(CO)5W(P(C₆H₅)2C(NC₆H₅)SCH₂CO₂CH₃)

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