C₂₃H₃₇ClHgO₄Si

Base Information

• Chemical Name: C₂₃H₃₇ClHgO₄Si
• CAS No.: 1391825-72-1
• Molecular Formula: C₂₃H₃₇ClHgO₄Si
• Molecular Weight: 641.673
• Mol file: 1391825-72-1.mol

Synonyms:C₂₃H₃₇ClHgO₄Si

Chemical Property of C₂₃H₃₇ClHgO₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of C₂₃H₃₇ClHgO₄Si

There total 6 articles about C₂₃H₃₇ClHgO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C23H38O4Si (1391825-71-0) → C23H37ClHgO4Si (1391825-72-1)

Guidance literature:

With mercury(II) diacetate; In tetrahydrofuran; at 20 ℃; for 2h; diastereoselective reaction;

DOI:10.1007/s11164-012-0702-y

Reference yield:

C19H26O6 (909576-58-5) → C23H37ClHgO4Si (1391825-72-1)

Guidance literature:

Multi-step reaction with 7 steps

1.1: sodium; naphthalene / tetrahydrofuran / 0 °C

2.1: sodium hydride / 3 h / 20 °C

3.1: sodium hydride; carbon disulfide; methyl iodide / tetrahydrofuran / 2 h / 0 °C

3.2: 3 h / 90 °C

4.1: toluene-4-sulfonic acid / tetrahydrofuran; water / 2 h / 60 °C

4.2: 10 h / 0 - 20 °C

5.1: tetrahydrofuran / 10 h / 0 - 20 °C

6.1: dmap / dichloromethane / 2 h / 20 °C

7.1: mercury(II) diacetate / tetrahydrofuran / 2 h / 20 °C

With carbon disulfide; dmap; naphthalene; mercury(II) diacetate; sodium; sodium hydride; toluene-4-sulfonic acid; methyl iodide; In tetrahydrofuran; dichloromethane; water; 3.1: |Barton-McCombie Deoxygenation / 3.2: |Barton-McCombie Deoxygenation;

DOI:10.1007/s11164-012-0702-y

Reference yield:

C19H28O5 → C23H37ClHgO4Si (1391825-72-1)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrahydrofuran / 10 h / 0 - 20 °C

2: dmap / dichloromethane / 2 h / 20 °C

3: mercury(II) diacetate / tetrahydrofuran / 2 h / 20 °C

With dmap; mercury(II) diacetate; In tetrahydrofuran; dichloromethane;

DOI:10.1007/s11164-012-0702-y

upstream raw materials:

C₁₂H₂₀O₆

(1S)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)pent-4-en-1-ol

C₁₉H₂₆O₆

C₁₉H₂₆O₆

Downstream raw materials:

C₂₃H₃₈O₅Si