2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)}

Base Information

• Chemical Name: 2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)}
• CAS No.: 80612-37-9
• Molecular Formula: C₁₁H₁₁FeO₃P*2K
• Molecular Weight: 356.224
• Mol file: 80612-37-9.mol

Synonyms:2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)}

Chemical Property of 2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)}

There total 3 articles about 2K⁽¹⁺⁾*{Fe(CO)3(P(C₆H₅)(CH₃)2)}^(2-)=K₂{Fe(CO)3(P(C₆H₅)(CH₃)2)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

{N(CH2CH3)4}(1+)*{HFe(CO)3(P(C6H5)(CH3)2)}(1-)={N(CH2CH3)4}{HFe(CO)3(P(C6H5)(CH3)2)} (80612-36-8) + potassium tri-sec-butyl-borohydride → 2K(1+)*{Fe(CO)3(P(C6H5)(CH3)2)}(2-)=K2{Fe(CO)3(P(C6H5)(CH3)2)} (80612-37-9)

Guidance literature:

In tetrahydrofuran; Fe-complex and with excess of K(sec-Bu)3BH (10 equiv) refluxed for 2 h in THF; elem. anal.;

DOI:10.1021/ja00368a059

Reference yield:

Dimethyl(phenyl)phosphine (672-66-2) → 2K(1+)*{Fe(CO)3(P(C6H5)(CH3)2)}(2-)=K2{Fe(CO)3(P(C6H5)(CH3)2)} (80612-37-9)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrahydrofuran

2: methanol

3: tetrahydrofuran

In tetrahydrofuran; methanol;

Reference yield:

Fe(CO)4(dimethylphenylphosphine) (37410-37-0) → 2K(1+)*{Fe(CO)3(P(C6H5)(CH3)2)}(2-)=K2{Fe(CO)3(P(C6H5)(CH3)2)} (80612-37-9)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol

2: tetrahydrofuran

In tetrahydrofuran; methanol;

upstream raw materials:

{N(CH₂CH₃)4}⁽¹⁺⁾*{HFe(CO)3(P(C₆H₅)(CH₃)2)}^(1-)={N(CH₂CH₃)4}{HFe(CO)3(P(C₆H₅)(CH₃)2)}

Dimethyl(phenyl)phosphine

Fe(CO)4(dimethylphenylphosphine)

Downstream raw materials:

{N(CH₂CH₃)4}⁽¹⁺⁾*{((C₆H₅)3Sn)Fe(CO)3(P(CH₃)2(C₆H₅))}^(1-)={N(CH₂CH₃)4}{((C₆H₅)3Sn)Fe(CO)3(P(CH₃)2(C₆H₅))}

(C₂H₅)4N⁽¹⁺⁾*(C₆H₅)3SnFe(CO)3(P(CH₃)2(C₆H₅))^(1-)=((C₂H₅)4N)((C₆H₅)3SnFe(CO)3(P(CH₃)2(C₆H₅)))