cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

Base Information

Chemical Name:cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate
CAS No.:117872-92-1
Molecular Formula:AsF₆*C₅₄H₄₈MnO₂P₄
Molecular Weight:1096.72
Hs Code.:

Synonyms:cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

Suppliers and Price of cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

There total 1 articles about cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: HMn(CO)2{(diphenylphosphino)ethane}2

: 437-15-0
triphenylmethylium hexafluoridoarsenate

: 117872-92-1
cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

Guidance literature:: In dichloromethane; Ph3C(+)AsF6(-) added portionwise to soln. of HMn(CO)2(DPPE)(+)AsF6(-) in CH2Cl2 at 0°C under Ar, mixt. stirred 1 h; vol. reduced (vac.), rapid chromy. of residual soln. (alumina, acetonitrile/diethyl ether, 0°C), collection of yellow band, pptn. with Et2O;

Reference yield: 70.0%

: 117872-92-1
cis-dicarbonylbis{bis(diphenylphosphino)ethane}manganese(I) hexafluoroarsenate

: 115162-69-1
{Mn(CO)2(η2-DPPE)(η1-DPPE)}(1-)

: HMn(CO)2{(diphenylphosphino)ethane}2

Guidance literature:: With tetra-n-butyl hexafluorophosphate; In acetonitrile; Electrochem. Process; controlled-potential reduction of the light green-yellow soln. at -2.0V until current fell to background level to give a very dark red soln., passage of 1.94 equiv. of charge/mol of Mn(CO)2(DPPE)(1+); products not isolated, detected by IR spect.; Kinetics;