C₅₂H₇₀O₁₀SSi

Base Information

Chemical Name:C₅₂H₇₀O₁₀SSi
CAS No.:1592771-97-5
Molecular Formula:C₅₂H₇₀O₁₀SSi
Molecular Weight:915.273
Hs Code.:

C<sub>52</sub>H<sub>70</sub>O<sub>10</sub>SSi

Synonyms:C₅₂H₇₀O₁₀SSi

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₅₂H₇₀O₁₀SSi

Chemical Property:

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Technology Process of C₅₂H₇₀O₁₀SSi

There total 32 articles about C₅₂H₇₀O₁₀SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1592771-29-3
C₅₅H₇₈O₁₀SSi₂

: 1592771-97-5
C₅₂H₇₀O₁₀SSi

Guidance literature:: With toluene-4-sulfonic acid; In methanol; dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1021/ol500788c

Reference yield:

: methyl 3-O-benzyl-5-O-(p-toluenesulfonyl)-2-deoxy-D-ribofuranoside

: 1592771-97-5
C₅₂H₇₀O₁₀SSi

Guidance literature:: Multi-step reaction with 11 steps

1: lithium triethylborohydride / tetrahydrofuran / 6.25 h / 20 - 45 °C / Inert atmosphere

2: boron trifluoride diethyl etherate / dichloromethane / 0.67 h / 0 - 20 °C / Inert atmosphere

3: 4-methyl-morpholine / dichloromethane / 2 h / 20 °C / Inert atmosphere

4: methyl iodide; sodium hydrogencarbonate / acetonitrile; water / 24 h / 20 °C

5: samarium diiodide / acetonitrile; methanol / 1 h / -20 °C / Inert atmosphere

6: 2,6-dimethylpyridine / dichloromethane / 0.75 h / 0 - 20 °C / Inert atmosphere

7: diisobutylaluminium hydride / dichloromethane; hexane / 0.75 h / -80 °C / Inert atmosphere

8: lithium chloride; triethylamine / acetonitrile / 5 h / 20 °C / Inert atmosphere

9: potassium tert-butylate; tert.-butylhydroperoxide / tetrahydrofuran / 16 h / -80 - -25 °C / Inert atmosphere

10: n-butyllithium / tetrahydrofuran; hexane; N,N,N,N,N,N-hexamethylphosphoric triamide / 0.67 h / -100 °C / Inert atmosphere

11: toluene-4-sulfonic acid / dichloromethane; methanol / 0.5 h / 20 °C

With 4-methyl-morpholine; 2,6-dimethylpyridine; tert.-butylhydroperoxide; n-butyllithium; samarium diiodide; boron trifluoride diethyl etherate; potassium tert-butylate; diisobutylaluminium hydride; lithium triethylborohydride; sodium hydrogencarbonate; toluene-4-sulfonic acid; triethylamine; lithium chloride; methyl iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; water; acetonitrile; 8: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1021/ol500788c

Reference yield:

: 1592771-01-1
(2R,3S)-3-(benzyloxy)-4-(1,3-dithian-2-yl)butan-2-ol

: 1592771-97-5
C₅₂H₇₀O₁₀SSi

Guidance literature:: Multi-step reaction with 12 steps

1: 4-methyl-morpholine / dichloromethane / 2 h / 20 °C / Inert atmosphere

2: methyl iodide; sodium hydrogencarbonate / acetonitrile; water / 24 h / 20 °C

3: samarium diiodide / acetonitrile; methanol / 1 h / -20 °C / Inert atmosphere

4: Dess-Martin periodane / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

5: sodium tetrahydroborate / dichloromethane; methanol / 0.5 h / -80 °C / Inert atmosphere

6: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

7: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

8: diisobutylaluminium hydride / dichloromethane; hexane / 0.75 h / -80 °C / Inert atmosphere

9: lithium chloride; triethylamine / acetonitrile / 5 h / 20 °C / Inert atmosphere

10: potassium tert-butylate; tert.-butylhydroperoxide / tetrahydrofuran / 16 h / -80 - -25 °C / Inert atmosphere

11: n-butyllithium / tetrahydrofuran; hexane; N,N,N,N,N,N-hexamethylphosphoric triamide / 0.67 h / -100 °C / Inert atmosphere

12: toluene-4-sulfonic acid / dichloromethane; methanol / 0.5 h / 20 °C

With 4-methyl-morpholine; 2,6-dimethylpyridine; tert.-butylhydroperoxide; sodium tetrahydroborate; n-butyllithium; samarium diiodide; potassium tert-butylate; potassium hexamethylsilazane; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; triethylamine; lithium chloride; methyl iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; water; toluene; acetonitrile; 4: |Dess-Martin Oxidation / 9: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1021/ol500788c