methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

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Chemical Name:methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester
CAS No.:165817-38-9
Molecular Formula:C₂₈H₃₈O₇
Molecular Weight:486.606
Hs Code.:

Synonyms:methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

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Chemical Property of methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

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Technology Process of methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

There total 3 articles about methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 132974-57-3
O-(methoxymethyl)glycolic acid

: 165817-37-8
(3R,4R,8S)-8-benzyloxy-4-(4-methoxybenzyloxy)non-1-en-3-ol

: 165817-38-9
methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 3h; Ambient temperature;
DOI:10.1016/0040-4039(95)00915-Y

Reference yield:

: 165817-36-7
(2R,4E,6S)-6-benzyloxy-2-(4-methoxybenzyloxy)hept-4-enoic acid methyl ester

: 165817-38-9
methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 82 percent / H₂; n-BuNH₂ / Pd/C / ethyl acetate / 3 h / 20 °C / 1551.49 Torr

2.1: DIBALH / diethyl ether / 1 h / -78 °C

2.2: 63 percent / tetrahydrofuran; diethyl ether / -78 - 20 °C

3.1: 93 percent / DMAP; DCC / CH₂Cl₂ / 3 h / 20 °C

With dmap; hydrogen; diisobutylaluminium hydride; N-butylamine; dicyclohexyl-carbodiimide; palladium on activated charcoal; In diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1021/jo010743i

Reference yield:

: 403694-63-3
(2R,6S)-6-benzyloxy-2-(4-methoxybenzyloxy)heptanoic acid methyl ester

: 165817-38-9
methoxymethoxyacetic acid (1R)-1-[(1R,5S)-5-benzyloxy-1-(4-methoxybenzyloxy)hexyl]allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: DIBALH / diethyl ether / 1 h / -78 °C

1.2: 63 percent / tetrahydrofuran; diethyl ether / -78 - 20 °C

2.1: 93 percent / DMAP; DCC / CH₂Cl₂ / 3 h / 20 °C

With dmap; diisobutylaluminium hydride; dicyclohexyl-carbodiimide; In diethyl ether; dichloromethane;
DOI:10.1021/jo010743i