(S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate

Base Information

Chemical Name:(S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate
CAS No.:119392-31-3
Molecular Formula:C₁₂H₂₂O₄
Molecular Weight:230.304
Hs Code.:2932999099
DSSTox Substance ID:DTXSID00559563
Wikidata:Q82442313
Mol file:119392-31-3.mol

Synonyms:119392-31-3;(S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate;ETHYL-6(S),7-ISOPROPYLIDENEDIOXY-HEPTANOATE;ethyl 5-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]pentanoate;ethyl (S)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate;DTXSID00559563

Suppliers and Price of (S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(S)-Ethyl5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate 95+%
1g
$ 772.00

Chemenu
ethyl(S)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate 95%
1g
$ 729.00

American Custom Chemicals Corporation
ETHYL-6(S),7-ISOPROPYLIDENEDIOXY-HEPTANOATE 98.00%
5MG
$ 500.96

Alichem
(S)-Ethyl5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate
1g
$ 646.84

Total 6 raw suppliers

Chemical Property of (S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate

Chemical Property:

Vapor Pressure:0.00452mmHg at 25°C
Refractive Index:1.434
Boiling Point:277.5°Cat760mmHg
Flash Point:114.9°C
PSA：44.76000
Density:0.989g/cm³
LogP:2.26140
Storage Temp.:2-8°C
XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:7
Exact Mass:230.15180918
Heavy Atom Count:16
Complexity:225

Purity/Quality:

98% ^*data from raw suppliers

(S)-Ethyl5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)CCCCC1COC(O1)(C)C
Isomeric SMILES:CCOC(=O)CCCC[C@H]1COC(O1)(C)C

Technology Process of (S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate

There total 3 articles about (S)-Ethyl 5-(2,2-dimethyl-1,3-dioxolan-4-yl)pentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 119392-30-2
ethyl 6(S),7-dihydroxy-6(S),7-O-(1-methylethylidene)-4(E)-heptenoate

: 119392-31-3
ethyl 6(S),7-dihydroxy-6(S),7-O-(1-methylethylidene)heptanoate

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; under 760 Torr; Ambient temperature;
DOI:10.1021/jo00271a032

Reference yield:

: 212579-64-1
(4R)-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)allyl alcohol

: 119392-31-3
ethyl 6(S),7-dihydroxy-6(S),7-O-(1-methylethylidene)heptanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / propanoic acid / 2.5 h / 137 °C

2: 90 percent / hydrogen / 10percent Pd/C / ethyl acetate / 760 Torr / Ambient temperature

With hydrogen; propionic acid; palladium on activated charcoal; In ethyl acetate;
DOI:10.1021/jo00271a032

Reference yield:

: 15186-48-8
2,3-isopropylidene-glyceraldehyde

: 119392-31-3
ethyl 6(S),7-dihydroxy-6(S),7-O-(1-methylethylidene)heptanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / tetrahydrofuran / 1.) RT, 3 h, 2.) reflux, 2 h

2: 84 percent / propanoic acid / 2.5 h / 137 °C

3: 90 percent / hydrogen / 10percent Pd/C / ethyl acetate / 760 Torr / Ambient temperature

With hydrogen; propionic acid; palladium on activated charcoal; In tetrahydrofuran; ethyl acetate;
DOI:10.1021/jo00271a032