4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

Base Information

Chemical Name:4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)
CAS No.:219489-06-2
Molecular Formula:C₆₂H₇₁NO₁₆
Molecular Weight:1086.24
Hs Code.:

Synonyms:4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

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Chemical Property of 4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

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Technology Process of 4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

There total 15 articles about 4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 219489-03-9
4-methoxyphenyl (2,3,4-tri-O-acetyl-6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

: 219489-06-2
4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

Guidance literature:: With sodium methylate; In methanol; at 22 ℃; for 1.5h;
DOI:10.1021/jo981203x

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 219489-06-2
4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

Guidance literature:: Multi-step reaction with 8 steps

1: 92 percent / TsOH / acetonitrile / 2 h

2: BH₃NMe₃, AlCl₃ / tetrahydrofuran / 1 h / 60 °C

3: pyridine / 20 h

4: 1.) AgOTf, 2.) MeSBr / 1.) CH₂Cl₂, -78 deg C, 5 min, 2.) CH₂Cl₂, 1,2-dichloroethane, -70 deg C, 2 h

5: 1,2-diaminoethane / ethanol / 3 h / 60 °C

6: 69 mg / methanol; H₂O / 1 h / 22 °C

8: 89 percent / MeONa / methanol / 1.5 h / 22 °C

With aluminium trichloride; methanesulfonyl bromide; trimethylamine-borane; sodium methylate; silver trifluoromethanesulfonate; toluene-4-sulfonic acid; ethylenediamine; In tetrahydrofuran; pyridine; methanol; ethanol; water; acetonitrile;
DOI:10.1021/jo981203x

Reference yield:

: 16758-34-2
1-thiophenyl-β-D-galactopyranoside

: 219489-06-2
4-methoxyphenyl (6-O-benzyl-β-D-galactopyranosyl)-(1->4)-<2,3,4-tri-O-benzyl-α-L-fucopyranosyl>-(1->3)-(2-acetamido-2-deoxy-β-D-glucopyranoside)

Guidance literature:: Multi-step reaction with 8 steps

1: 92 percent / TsOH / acetonitrile / 2 h

2: BH₃NMe₃, AlCl₃ / tetrahydrofuran / 1 h / 60 °C

3: pyridine / 20 h

4: 1.) AgOTf, 2.) MeSBr / 1.) CH₂Cl₂, -78 deg C, 5 min, 2.) CH₂Cl₂, 1,2-dichloroethane, -70 deg C, 2 h

5: 1,2-diaminoethane / ethanol / 3 h / 60 °C

6: 69 mg / methanol; H₂O / 1 h / 22 °C

8: 89 percent / MeONa / methanol / 1.5 h / 22 °C

With aluminium trichloride; methanesulfonyl bromide; trimethylamine-borane; sodium methylate; silver trifluoromethanesulfonate; toluene-4-sulfonic acid; ethylenediamine; In tetrahydrofuran; pyridine; methanol; ethanol; water; acetonitrile;
DOI:10.1021/jo981203x