Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

Base Information

Chemical Name:Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate
CAS No.:128684-90-2
Molecular Formula:C₁₈H₃₆O₄Si
Molecular Weight:344.567
Hs Code.:

Synonyms:Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

Chemical Property:

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Technology Process of Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

There total 13 articles about Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 128684-89-9
(1R,3R,4R) methyl 4-hydroxy-3-methoxy-1-cyclohexanecarboxylate

: 128684-90-2
Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 1h;
DOI:10.1021/ja00170a024

Reference yield: 91.0%

: 128684-89-9
(1R,3R,4R) methyl 4-hydroxy-3-methoxy-1-cyclohexanecarboxylate

: 130649-59-1
TIPSOTf

: 128684-90-2
Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/jo00127a031

Reference yield:

: 128684-88-8
methyl (1R,3R)-3-methoxycyclohex-4-enecarboxylate

: 128684-90-2
Methyl (1R,3R,4R)-3-methoxy-4-<(triisopropylsilyl)oxy>cyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BH₃*THF, 2.) 3 N aq. NaOH, 30percent H₂O₂ / 1.) THF, -78 deg C, 40 min; 0 deg C 1 h, 2.) r.t., 3 h

2: 91 percent / Et₃N / CH₂Cl₂ / 1 h / 0 °C

With sodium hydroxide; borane-THF; dihydrogen peroxide; triethylamine; In dichloromethane;
DOI:10.1021/jo00127a031