Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

Base Information

Chemical Name:Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester
CAS No.:349078-78-0
Molecular Formula:C₁₇H₂₄O₄
Molecular Weight:292.375
Hs Code.:

Synonyms:Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

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Chemical Property of Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

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Technology Process of Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

There total 1 articles about Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 108-05-4,9003-20-7
vinyl acetate

: (Z)-4-(3,4-Dimethoxy-phenyl)-5-methyl-hex-3-en-2-ol

: 349078-83-7
Acetic acid (Z)-(S)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

: 349078-78-0
Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

Guidance literature:: With lipase PS (Burkholderia cepacia); In diethyl ether; at 20 ℃; for 18h; Enzymatic reaction;
DOI:10.1002/1099-0690(200104)2001:7<1349::AID-EJOC1349>3.0.CO;2-9

Reference yield: 63.0%

: 349078-78-0
Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

: 349078-84-8
(E,R)-(-)-3-(3,4-dimethoxyphenyl)-3-isopropylhex-4-enoic acid

Guidance literature:: Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.0833333h;

With chloro-trimethyl-silane; In tetrahydrofuran; for 3h; Heating;

In methanol; at 20 ℃; for 0.166667h; Further stages.;
DOI:10.1002/1099-0690(200104)2001:7<1349::AID-EJOC1349>3.0.CO;2-9

Reference yield:

: 349078-78-0
Acetic acid (Z)-(R)-3-(3,4-dimethoxy-phenyl)-1,4-dimethyl-pent-2-enyl ester

: 36622-29-4,56949-77-0
(S)-verapamil

Guidance literature:: Multi-step reaction with 15 steps

1.1: lithium diisopropylamide / tetrahydrofuran / 0.08 h / -78 °C

1.2: trimethylchlorosilane / tetrahydrofuran / 3 h / Heating

1.3: 63 percent / methanol / 0.17 h / 20 °C

2.1: 97 percent / diethyl ether

3.1: 89 percent / DIBAL-H / toluene / 1 h / 20 °C

4.1: 92 percent / pyridine

5.1: 85 percent / dimethylsulfoxide / 2 h / 80 °C

6.1: 81 percent / 20percent KOH / bis-(2-hydroxy-ethyl) ether / 1 h / Heating

7.1: 98 percent / diethyl ether

8.1: 84 percent / DIBAL-H / toluene / 1 h / 20 °C

9.1: 98 percent / pyridine

10.1: 68 percent / ozone; triphenylphosphane / CH₂Cl₂; methanol

11.1: hydroxylamine hydrochloride; sodium acetate / ethanol

12.1: 1.52 g / sodium acetate / acetic anhydride / Heating

13.1: potassium hydroxide / methanol / 2 h / Heating

14.1: 95 percent / triphenylphosphane / CCl₄ / 2 h / Heating

15.1: 91 percent / 1 h / 130 °C

With pyridine; potassium hydroxide; hydroxylamine hydrochloride; sodium acetate; diisobutylaluminium hydride; ozone; triphenylphosphine; lithium diisopropyl amide; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; ethanol; dichloromethane; acetic anhydride; dimethyl sulfoxide; toluene; diethylene glycol; 1.1: Ireland rearrangement;
DOI:10.1002/1099-0690(200104)2001:7<1349::AID-EJOC1349>3.0.CO;2-9