3',4'-(DIDECYLOXY)ACETOPHENONE

Base Information

• Chemical Name: 3',4'-(DIDECYLOXY)ACETOPHENONE
• CAS No.: 118468-33-0
• Molecular Formula: C28H48 O3
• Molecular Weight: 432.687
• Mol file: 118468-33-0.mol

Synonyms:1,2-Didecyloxy-4-acetylbenzene

Chemical Property of 3',4'-(DIDECYLOXY)ACETOPHENONE

Chemical Property:

• Melting Point: 61-65 °C
• Refractive Index: 1.5460 (estimate)
• Boiling Point: 506.29°C (rough estimate)
• PSA: 35.53000
• Density: 0.9416 (rough estimate)
• LogP: 8.92820

Purity/Quality:

98%min ^*data from raw suppliers

3',4'-(DIDECYLOXY)ACETOPHENONE 98.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3',4'-(DIDECYLOXY)ACETOPHENONE

There total 5 articles about 3',4'-(DIDECYLOXY)ACETOPHENONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Iododecane (2050-77-3) + 1-(3,4-dihydroxyphenyl)ethan-1-one (1197-09-7) → di-decyloxy-3,4 acetophenone (118468-33-0)

Guidance literature:

1-(3,4-dihydroxyphenyl)ethan-1-one; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 5h;

Iododecane; In N,N-dimethyl-formamide; at 60 ℃;

DOI:10.1246/bcsj.20150316

Reference yield:

1-bromo dodecane (112-29-8) + 1-(3,4-dihydroxyphenyl)ethan-1-one (1197-09-7) → di-decyloxy-3,4 acetophenone (118468-33-0)

Guidance literature:

With sodium hydroxide; In N,N-dimethyl-formamide; Heating;

DOI:10.1016/S0040-4039(01)00640-2

Reference yield:

1-bromo dodecane (112-29-8) → di-decyloxy-3,4 acetophenone (118468-33-0)

Guidance literature:

Multi-step reaction with 2 steps

1: KOH, aliquat 336 / neat (no solvent)

2: AlCl₃ / CH₂Cl₂

With potassium hydroxide; aluminium trichloride; Aliquat 336; In dichloromethane;

upstream raw materials:

1,2-bis-decyloxy-benzene

acetyl chloride

1-bromo dodecane

1-(3,4-dihydroxyphenyl)ethan-1-one

Downstream raw materials:

tetradecyloxy-3,4,3',4' chalcone

1,2-bis(decyloxy)-4-ethynyl-benzene