1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene

Base Information

• Chemical Name: 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene
• CAS No.: 114832-98-3
• Molecular Formula: C₇₃H₁₀₄O₄
• Molecular Weight: 1045.63
• Mol file: 114832-98-3.mol

Synonyms:1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene

Chemical Property of 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene

There total 13 articles about 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methyl-2-butenylmagnesium chloride (35189-96-9) + Benzenesulfonic acid (4E,8E,12E,16E,20E,24E,28E,32E)-34-(2,5-bis-benzyloxy-3,4-dimethoxy-6-methyl-phenyl)-1-isopropenyl-4,8,12,16,20,24,28,32-octamethyl-tetratriaconta-4,8,12,16,20,24,28,32-octaenyl ester → 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene (114832-98-3)

Guidance literature:

With dilithium tetrachlorocuprate; In tetrahydrofuran; at -70 ℃; for 0.5h; Yield given;

DOI:10.1007/BF00978441

Reference yield:

1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(37'-phenylsulfonyl-3',7',11',15',19',23',27',31',35',39'-decamethyltetraconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,34'E,38'-decaenyl)benzene (116883-28-4) → 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene (114832-98-3) + 1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(3',7',11',15',19',23',27',31',35',39'-decamethyltetraconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,34'E,37'E-decaenyl)benzene (116854-29-6)

Guidance literature:

With sodium; In tetrahydrofuran; ethanol; at -70 ℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00965388

Reference yield:

3-methyl-2-butenylmagnesium chloride (35189-96-9) + 1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(36'-chloro-3',7',11',15',19',23',27',31',35'-nonamethylhexatriaconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,34'E-nonaenyl)benzene (116854-26-3) → 1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(3',7',11',15',19',23',27',31',35'-nonamethylhexatriaconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,33'E,35'-decaenyl)-benzene (124460-25-9) + 1,4-Bis-benzyloxy-2-((2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-methyl-benzene (114832-98-3) + 1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(34'-isopropenyl-3',7',11',15',19',23',27',31',37'-nonamethyloctatriaconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,36'-nonaenyl)benzene (124891-88-9)

Guidance literature:

copper(l) chloride; In tetrahydrofuran; at -70 ℃; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00978441

upstream raw materials:

3-methyl-2-butenylmagnesium chloride

1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(36'-chloro-3',7',11',15',19',23',27',31',35'-nonamethylhexatriaconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,34'E-nonaenyl)benzene

1,4-dibenzyloxy-2,3-dimethoxy-5-methyl-6-(37'-phenylsulfonyl-3',7',11',15',19',23',27',31',35',39'-decamethyltetraconta-2'E,6'E,10'E,14'E,18'E,22'E,26'E,30'E,34'E,38'-decaenyl)benzene

3-methyl-1-(phenylsulfonyl)but-2-ene

Downstream raw materials:

ubidecarenone

34'Z-ubiquinone-10

ubiquinol