Bicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 7,7-dimethyl-, (1R,6S)-

Base Information

Chemical Name:Bicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 7,7-dimethyl-, (1R,6S)-
CAS No.:554-58-5
Molecular Formula:C₁₀H₁₄O₂
Molecular Weight:166.22
Hs Code.:

Synonyms:3-Norcarene-3-carboxylicacid, 7,7-dimethyl- (7CI,8CI); Bicyclo[4.1.0]hept-3-ene-3-carboxylic acid,7,7-dimethyl-, (1R)-; Isochamic acid (6CI)

Suppliers and Price of Bicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 7,7-dimethyl-, (1R,6S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 7,7-dimethyl-, (1R,6S)-

Chemical Property:

Melting Point:105-106 °C
Boiling Point:269.1±9.0 °C(Predicted)
PSA：37.30000
Density:1.129±0.06 g/cm3(Predicted)
LogP:2.06340

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Bicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 7,7-dimethyl-, (1R,6S)-

There total 3 articles about Bicyclo[4.1.0]hept-3-ene-3-carboxylicacid, 7,7-dimethyl-, (1R,6S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 5114-01-2,14595-13-2,116947-42-3
(+/-)-3-caren-10-al

: 498-12-4,554-58-5,38859-06-2
(+/-)-chaminic acid

Guidance literature:: With sodium hydroxide; silver(l) oxide; In methanol; water; at 25 ℃; for 3h;
DOI:10.1007/BF01455479

Reference yield:

: 116872-39-0
(+/-)-10-phenylsulfonylcar-3-ene

: 498-12-4,554-58-5,38859-06-2
(+/-)-chaminic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / P(OEt)3, Et₂NH / methanol / 10 h / 55 °C

2: 49 percent / CrO₃, HMDS / CH₂Cl₂ / 1 h / 25 °C

3: 47 percent / Ag₂O, NaOH / H₂O; methanol / 3 h / 25 °C

With chromium(VI) oxide; sodium hydroxide; diethylamine; 1,1,1,3,3,3-hexamethyl-disilazane; silver(l) oxide; triethyl phosphite; In methanol; dichloromethane; water;
DOI:10.1007/BF01455479

Reference yield:

: 1753-35-1,4017-83-8,22339-03-3,22626-38-6,38741-15-0,116947-41-2,116947-43-4,697298-84-3
(+/-)-trans-3⁽¹⁰⁾-carene-4-ol

: 498-12-4,554-58-5,38859-06-2
(+/-)-chaminic acid

Guidance literature:: Multi-step reaction with 2 steps

1: 49 percent / CrO₃, HMDS / CH₂Cl₂ / 1 h / 25 °C

2: 47 percent / Ag₂O, NaOH / H₂O; methanol / 3 h / 25 °C

With chromium(VI) oxide; sodium hydroxide; 1,1,1,3,3,3-hexamethyl-disilazane; silver(l) oxide; In methanol; dichloromethane; water;
DOI:10.1007/BF01455479