dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron

Base Information

• Chemical Name: dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron
• CAS No.: 12213-19-3
• Molecular Formula: C₂₆H₂₃FeO₂P
• Molecular Weight: 454.288
• Mol file: 12213-19-3.mol

Synonyms:dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron

Chemical Property of dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron

There total 5 articles about dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

dicarbonyl{O-4-η-((E)-4-phenylbut-3-en-2-one)}(triphenylphosphine)iron + cyclohexa-1,3-diene (1165952-91-9) → (cyclohexa-1,3-diene)iron tricarbonyl (12152-72-6) + dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron (12213-19-3)

Guidance literature:

In Petroleum ether; under Ar, Fe complex reacted with 40-fold molar excess of 1,3-C6H8 at 70°C in petroleum ether / kinetics monitored by IR at 70.1°C; filtration through Hiflow, evapn., chromy. (SiO2, benzene), crystn. from MeOH; elem. anal.; Kinetics;

DOI:10.1016/0022-328X(84)80113-8

Reference yield: 90.0%

(benzylideneacetone)dicarbonyl(triphenylphosphine)iron(0) (93984-16-8,67663-91-6,56556-41-3) + cyclohexa-1,3-diene (1165952-91-9) → dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron (12213-19-3)

Guidance literature:

In benzene; N2-atmosphere; refluxing of Fe-complex with 10 equiv. of diene (12 h); chromy. (SiO2, C6H6);

DOI:10.1039/DT9780000369

Reference yield: 71.0%

(cyclohexa-1,3-diene)iron tricarbonyl (12152-72-6) → dicarbonyl(triphenylphosphine)(η(4)-cyclohexa-1,3-diene)iron (12213-19-3)

Guidance literature:

With triphenylphosphine; In further solvent(s); refluxing in cyclohexanol, 15 h;

DOI:10.1016/S0022-328X(00)99488-9

upstream raw materials:

(benzylideneacetone)dicarbonyl(triphenylphosphine)iron⁽⁰⁾

cyclohexa-1,3-diene

(cyclohexa-1,3-diene)iron tricarbonyl

triphenylphosphine

Downstream raw materials:

dicarbonyl(triphenylphosphine)(η(5)-cyclohexa-1,3-dienyl)iron tetrafluoroborate