μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Base Information

Chemical Name:μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)
CAS No.:637765-00-5
Molecular Formula:C₁₁₀H₁₀₄N₁₀Zn₂
Molecular Weight:1696.88
Hs Code.:

μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Synonyms:μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Chemical Property of μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Technology Process of μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

There total 4 articles about μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 637765-04-9
[ZnN₄C₂₀H₈(C₆H₃(C(CH₃)3)2)2C₆H₄CN]2

: 637765-00-5
μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; scandium tris(trifluoromethanesulfonate); In toluene; 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, Sc(OSO2CF3)3, toluene, reflux, 30 min;
DOI:10.1002/anie.200352265

Reference yield: 99.0%

: 637765-04-9
μ-[15,15'-bis(3-cyanophenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 637765-00-5
μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With Sc(OCOCF₃)3; 2,3-dichloro-5,6-dicyano-p-benzoquinone; In toluene; Sc-triflate ad benzoquinone-compound were added under N2 to a soln. of complex in dry toluene, the mixt. was heated to reflux for 30 min, cooledto 25°C; diluted with pyridine, washed with H2O and satd. aq. NaCl soln., dired (Na2SO4), evapd. in vac.; chromy. (silica gel; CH2Cl2, 1% v/v (C2H5)3N and Al2O3; cyclohexane/CH2Cl2 98:2, 1% v/v (C2H5)3N), pptn. from CHCl3 by dropwise addn. of hexane;
DOI:10.1002/hlca.200590144

Reference yield: 89.0%

: 637765-01-6
ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN

: 637765-00-5
μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; scandium tris(trifluoromethanesulfonate); In toluene; 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, Sc(OSO2CF3)3, toluene, reflux, 30 min;
DOI:10.1002/anie.200352265