methyl-1-hexenylisopropoxyborane

Base Information

Chemical Name:methyl-1-hexenylisopropoxyborane
CAS No.:148058-10-0
Molecular Formula:C₁₀H₂₁BO
Molecular Weight:168.087
Hs Code.:

Synonyms:methyl-1-hexenylisopropoxyborane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl-1-hexenylisopropoxyborane

Chemical Property:

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Technology Process of methyl-1-hexenylisopropoxyborane

There total 2 articles about methyl-1-hexenylisopropoxyborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 917-54-4
methyllithium

: 91083-27-1
(E)-1-hexenyldiisopropoxyborane

: dimethylisopropoxyborane

: 5419-55-6
Triisopropyl borate

: 148058-10-0
methyl-1-hexenylisopropoxyborane

: 86595-27-9
diisopropoxymethylborane

Guidance literature:: With CH₃SO₃H or HCl or CH₃COCl or ClCH₂COCl or Cl₃CCOCl; In diethyl ether; addn. of CH3Li to soln. of C6H11B(OCH(CH3)2)2 (2.5 mmol) in ether at -78°C via syringe; stirring at -78°C for 3 h; addn. of acid (further acids investigated: ClCH2COCl, (CH3)3SiCl); warming slowly to room temp.; stirring at room temp.;; not isolated; product distribution is determined by 11B-NMR for various conditions (temp. at which acid is added, amt. of CH3Li, amt. of acid);;
DOI:10.1021/om00028a021

Reference yield:

: 917-54-4
methyllithium

: 91083-27-1
(E)-1-hexenyldiisopropoxyborane

: dimethylisopropoxyborane

: 5419-55-6
Triisopropyl borate

: C₆H₁₁B(CH₃)2

: 148058-10-0
methyl-1-hexenylisopropoxyborane

: 86595-27-9
diisopropoxymethylborane

Guidance literature:: With methanesulfonic acid; In hexane; byproducts: (CH3)3B; dropwise addn. of CH3Li (1 equiv.) to soln. of C6H11B(OCH(CH3)2)2 (2.5 mmol) in hexane at -78°C via syringe; stirring at -78°C for 3 h; addn. of CH3SO3H at 0/25°C; warming slowly to room temp.; stirring at room temp.;; not isolated; product distribution (depending on temp. at which acid is added) is determined by 11B-NMR;;
DOI:10.1021/om00028a021