(Z)-7-benzyloxy-5-methyl-5-heptenenitrile

Base Information

Chemical Name:(Z)-7-benzyloxy-5-methyl-5-heptenenitrile
CAS No.:73454-49-6
Molecular Formula:C₁₅H₁₉NO
Molecular Weight:229.322
Hs Code.:

Synonyms:(Z)-7-benzyloxy-5-methyl-5-heptenenitrile

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Chemical Property of (Z)-7-benzyloxy-5-methyl-5-heptenenitrile

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Technology Process of (Z)-7-benzyloxy-5-methyl-5-heptenenitrile

There total 7 articles about (Z)-7-benzyloxy-5-methyl-5-heptenenitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 143-33-9,25596-52-5
sodium cyanide

: 73454-44-1
6-benzyloxy-4-methyl-4Z-hexen-1-ol p-toluenesulfonate

: 73454-49-6
(Z)-7-benzyloxy-5-methyl-5-heptenenitrile

Guidance literature:: In N,N-dimethyl-formamide; at 98 ℃; for 24h;
DOI:10.1021/jo01301a028

Reference yield: 96.0%

: 143-33-9,25596-52-5
sodium cyanide

: 73454-45-2
6-iodo-3-methyl-2Z-hexen-1-ol benzyl ether

: 73454-49-6
(Z)-7-benzyloxy-5-methyl-5-heptenenitrile

Guidance literature:: In N,N-dimethyl-formamide; at 20 ℃; for 1h;
DOI:10.1039/b605346g

Reference yield:

: 106-25-2
Nerol

: 73454-49-6
(Z)-7-benzyloxy-5-methyl-5-heptenenitrile

Guidance literature:: Multi-step reaction with 5 steps

1: NaH / DME 1) 80-85 deg C/ 1.5 h 2a) 1h reflux 2b) 16 h at r.t.

2: 1) O₃ / pyridine 2) Me₂S / 1) CH₂Cl₂ / -78 deg C 2) r.t./overnight

3: 87 percent / NaBH₄ / ethanol / 3.5 h / Ambient temperature

4: 93 percent / pyridine / 24 h / 0 °C

5: 100 percent / dimethylformamide / 24 h / 98 °C

With pyridine; sodium tetrahydroborate; dimethylsulfide; sodium hydride; ozone; In pyridine; ethanol; N,N-dimethyl-formamide;
DOI:10.1021/jo01301a028