Di-tert-butyl tartrate

Base Information

Chemical Name:Di-tert-butyl tartrate
CAS No.:117384-46-0
Molecular Formula:C12H22 O6
Molecular Weight:262.303
Hs Code.:
NSC Number:134488
DSSTox Substance ID:DTXSID40300051
Nikkaji Number:J267.498J
Mol file:117384-46-0.mol

Synonyms:di-tert-butyl tartrate;ditert-butyl 2,3-dihydroxybutanedioate;NSC134488;di-tert.-butyl tartrate;(S,S)-Di-tert-butyl-tartrat;SCHEMBL1845280;DTXSID40300051;ITWOKJQQGHCDBL-UHFFFAOYSA-N;AKOS032961389;NSC-134488;SB45482;FT-0625622;FT-0628019

Suppliers and Price of Di-tert-butyl tartrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(-)-DI-TERT-BUTYL D-TARTRATE 95.00%
1G
$ 773.73

Total 14 raw suppliers

Chemical Property of Di-tert-butyl tartrate

Chemical Property:

Vapor Pressure:2.34E-05mmHg at 25°C
Melting Point:90-92 °C(lit.)
Refractive Index:1.47
Boiling Point:321.8°Cat760mmHg
PKA:11.44±0.20(Predicted)
Flash Point:109.2°C
PSA：93.06000
Density:1.143g/cm³
LogP:0.39160
XLogP3:0.9
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:7
Exact Mass:262.14163842
Heavy Atom Count:18
Complexity:278

Purity/Quality:

97% ^*data from raw suppliers

(-)-DI-TERT-BUTYL D-TARTRATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)OC(=O)C(C(C(=O)OC(C)(C)C)O)O

Technology Process of Di-tert-butyl tartrate

There total 2 articles about Di-tert-butyl tartrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: O,O′-diacetyl di-tert-butyl meso-tartrate

: 117384-45-9,117384-46-0
di-tert-butyl meso-tartrate

Guidance literature:: In methanol; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/acs.joc.9b00827

Reference yield:

: (2S,3S)-2,3-Bis-(2-chloro-acetoxy)-succinic acid di-tert-butyl ester

: 117384-46-0
di-tert-butyl D-tartrate

Guidance literature:: With potassium carbonate; In methanol; at 0 ℃; for 0.283333h;
DOI:10.1016/S0040-4020(97)90390-2

Reference yield: 92.0%

: 2746-25-0
p-Methoxybenzyl bromide

: 117384-46-0
di-tert-butyl D-tartrate

: 644981-36-2
di-tert-butyl (2S,3S)-2-hydroxy-3-(4-methoxybenzyl)oxybutanedioate

Guidance literature:: di-tert-butyl D-tartrate; With di(n-butyl)tin oxide; In toluene; for 2h; Heating;

p-Methoxybenzyl bromide; With cesium fluoride; In N,N-dimethyl-formamide; for 10h;
DOI:10.1002/anie.200352629