(3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

Base Information

Chemical Name:(3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine
CAS No.:952716-02-8
Molecular Formula:C₁₈H₂₃NO₅
Molecular Weight:333.384
Hs Code.:

Synonyms:(3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

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Chemical Property of (3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

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Technology Process of (3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

There total 6 articles about (3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₄H₂₄O₁₂S₂

: 952716-02-8
(3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

Guidance literature:: Multi-step reaction with 4 steps

1: 3.46 g / sodium iodide / butan-2-one / 5 h / Heating

2: 90 percent / NaBH₄ / 2-methyl-propan-2-ol; methanol / 2 h / Heating

3: oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -65 - 20 °C

4: 440 mg / ethanol / 26 h

With sodium tetrahydroborate; oxalyl dichloride; dimethyl sulfoxide; triethylamine; sodium iodide; In methanol; ethanol; dichloromethane; butanone; tert-butyl alcohol; 3: Swern oxidation;
DOI:10.1021/jo070846m

Reference yield:

: 952716-01-7
(3aR,5R,6S,6aR)-2-(2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy)-ethanol

: 952716-02-8
(3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

Guidance literature:: Multi-step reaction with 2 steps

1: oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -65 - 20 °C

2: 440 mg / ethanol / 26 h

With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In ethanol; dichloromethane; 1: Swern oxidation;
DOI:10.1021/jo070846m

Reference yield:

: 952716-00-6
(3aR,5R,6S,6aR)-[2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy]-acetic acid methyl ester

: 952716-02-8
(3aR,3bS,6R,9S,9aS,10aR)-7-benzyl-2,2-dimethylperhydro-6,9-methano-1,3-dioxolo[4',5':4,5]furo[2,3-d][1,5,2]dioxazocine

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / NaBH₄ / 2-methyl-propan-2-ol; methanol / 2 h / Heating

2: oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -65 - 20 °C

3: 440 mg / ethanol / 26 h

With sodium tetrahydroborate; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In methanol; ethanol; dichloromethane; tert-butyl alcohol; 2: Swern oxidation;
DOI:10.1021/jo070846m