1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

Base Information

Chemical Name:1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene
CAS No.:1628897-28-8
Molecular Formula:C₂₆H₄₄N₆O₁₀
Molecular Weight:600.67
Hs Code.:

Synonyms:1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

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Chemical Property of 1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

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Technology Process of 1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

There total 6 articles about 1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 775324-81-7
1,4-bis(chloromethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

: 1628897-28-8
1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 80 ℃; for 18h;
DOI:10.1002/ejoc.201402140

Reference yield:

: 14753-51-6
2,5-dibromohydroquinone

: 1628897-28-8
1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium carbonate / N,N-dimethyl acetamide / 2.5 h / 140 °C / Microwave irradiation

2.1: n-butyllithium / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C

2.2: 2.5 h / -78 - 25 °C

3.1: lithium aluminium tetrahydride / diethyl ether / 4 h / 25 °C / Reflux

4.1: thionyl chloride; pyridine / dichloromethane / 18 h / 25 °C

5.1: sodium azide / N,N-dimethyl-formamide / 18 h / 80 °C

With pyridine; lithium aluminium tetrahydride; n-butyllithium; thionyl chloride; sodium azide; potassium carbonate; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl acetamide; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.201402140

Reference yield:

: 1246398-04-8
2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)terephthalaldehyde

: 1628897-28-8
1,4-bis(azidomethyl)-2,5-bis-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)benzene

Guidance literature:: Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / diethyl ether / 4 h / 25 °C / Reflux

2: thionyl chloride; pyridine / dichloromethane / 18 h / 25 °C

3: sodium azide / N,N-dimethyl-formamide / 18 h / 80 °C

With pyridine; lithium aluminium tetrahydride; thionyl chloride; sodium azide; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.201402140