MnC₆H₅NNH(CO)3(P(OC₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=Mn(C₆H₅NNH)(CO)3(P(OC₆H₅)3)2(BF₄)

Base Information

• Chemical Name: MnC₆H₅NNH(CO)3(P(OC₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=Mn(C₆H₅NNH)(CO)3(P(OC₆H₅)3)2(BF₄)
• CAS No.: 350579-63-4
• Molecular Formula: BF₄*C₄₅H₃₆MnN₂O₉P₂
• Molecular Weight: 952.479
• Mol file: 350579-63-4.mol

Synonyms:MnC₆H₅NNH(CO)3(P(OC₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=Mn(C₆H₅NNH)(CO)3(P(OC₆H₅)3)2(BF₄)

Chemical Property of MnC₆H₅NNH(CO)3(P(OC₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=Mn(C₆H₅NNH)(CO)3(P(OC₆H₅)3)2(BF₄)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

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Technology Process of MnC₆H₅NNH(CO)3(P(OC₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=Mn(C₆H₅NNH)(CO)3(P(OC₆H₅)3)2(BF₄)

There total 1 articles about MnC₆H₅NNH(CO)3(P(OC₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=Mn(C₆H₅NNH)(CO)3(P(OC₆H₅)3)2(BF₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

HMn(CO)3{P(C6H5O)3}2 (16972-18-2,16923-76-5,17250-37-2) + benzenediazonium tetrafluoroborate (369-57-3) → MnC6H5NNH(CO)3(P(OC6H5)3)2(1+)*BF4(1-)=Mn(C6H5NNH)(CO)3(P(OC6H5)3)2(BF4) (350579-63-4)

Guidance literature:

In dichloromethane; CH2Cl2 was added to a mixt. of complex and diazonium salt, the mixt. wasstirred for 2 h at room temp., evapd., treated with ethanol, NaBPh4 in ethanol was added (inert atm.); the soln. was cooled to -25°C, ppt. was filtered, crystd. from CH2Cl2-ethanol; elem. anal.;

DOI:10.1016/S0022-328X(00)00943-8

Reference yield: 75.0%

MnC6H5NNH(CO)3(P(OC6H5)3)2(1+)*BF4(1-)=Mn(C6H5NNH)(CO)3(P(OC6H5)3)2(BF4) (350579-63-4) → Mn(C6H5N2)(CO)2(P(OC6H5)3)2 (350579-80-5)

Guidance literature:

With triethylamine; In dichloromethane; byproducts: (NH(C2H5)3)(B(C6H5)4), CO; an excess of triethylamine was added to a soln. of complex in CH2Cl2, the mixt. was stirred for about 2 h (inert atm.); the solvent was removed under reduced pressure, the solid was trituratedwith benzene, filtered, the filtrate was evapd. to dryness, treated wit h ethanol, cooled to -25°C, crystals were filtered, dried in vac.; elem. anal.;

DOI:10.1016/S0022-328X(00)00943-8

upstream raw materials:

HMn(CO)3{P(C₆H₅O)3}2

benzenediazonium tetrafluoroborate

Downstream raw materials:

Mn(C₆H₅N₂)(CO)2(P(OC₆H₅)3)2