(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

Base Information

Chemical Name:(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde
CAS No.:683805-32-5
Molecular Formula:C₂₉H₂₈O₈
Molecular Weight:504.537
Hs Code.:

Synonyms:(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

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Chemical Property of (4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

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Technology Process of (4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

There total 4 articles about (4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 683805-31-4
[(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthren-5-yl]-methanol

: 683805-32-5
(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.333333h;
DOI:10.1016/j.tet.2004.01.017

Reference yield:

: 683805-30-3
(4aR,5R,6R,11bR)-5-(Methoxy-phenyl-methoxymethyl)-2-phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene

: 683805-32-5
(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / acetic acid / H₂O; CH₂Cl₂ / 96 h / 20 °C

2: 87 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.33 h / 20 °C

With Dess-Martin periodane; acetic acid; In dichloromethane; water; 2: Dess-Martin oxidation;
DOI:10.1016/j.tet.2004.01.017

Reference yield:

: 518-28-5
podofilox

: 683805-32-5
(4aR,5R,6R,11bR)-2-Phenyl-6-(3,4,5-trimethoxy-phenyl)-4a,5,6,11b-tetrahydro-4H-1,3,8,10-tetraoxa-cyclopenta[b]phenanthrene-5-carbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 60 percent / LAH / tetrahydrofuran / 2.5 h / 0 °C

2: 73 percent / p-toluenesulfonic aicd monohydrate / 0.67 h / 20 °C

3: 66 percent / acetic acid / H₂O; CH₂Cl₂ / 96 h / 20 °C

4: 87 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.33 h / 20 °C

With lithium aluminium tetrahydride; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; In tetrahydrofuran; dichloromethane; water; 4: Dess-Martin oxidation;
DOI:10.1016/j.tet.2004.01.017