tetracarbonyl(triphenyl phosphite)manganate(-I) anion

Base Information

Chemical Name:tetracarbonyl(triphenyl phosphite)manganate(-I) anion
CAS No.:71427-83-3
Molecular Formula:C₂₂H₁₅MnO₇P
Molecular Weight:477.269
Hs Code.:

Synonyms:tetracarbonyl(triphenyl phosphite)manganate(-I) anion

Suppliers and Price of tetracarbonyl(triphenyl phosphite)manganate(-I) anion

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tetracarbonyl(triphenyl phosphite)manganate(-I) anion

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tetracarbonyl(triphenyl phosphite)manganate(-I) anion

There total 1 articles about tetracarbonyl(triphenyl phosphite)manganate(-I) anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15529-62-1,15228-70-3
Mn₂(CO)8(triphenyl phosphite)2

: 71427-83-3
tetracarbonyl(triphenyl phosphite)manganate(-I) anion

Guidance literature:: With sodium amalgam; In not given; Mn2(CO)8(P(OPh)3)2 treated with sodioamalgam in THF or MeCN for 1-2 h inder Ar; excess Hg and amalgam removed, mixt. filtered through Celite under Ar atmosphere;
DOI:10.1021/om00152a010

Reference yield: 38.0%

: 71427-83-3
tetracarbonyl(triphenyl phosphite)manganate(-I) anion

: 71465-42-4
pentacarbonyl(diethylphenylphosphine)manganese(I) cation

: 104350-79-0
tetracarbonylhydrido(diethylphenylphosphine)manganese

: 15444-75-4
Mn₂(CO)8(diethylphenylphosphine)2

: 15529-62-1,15228-70-3
Mn₂(CO)8(triphenyl phosphite)2

: 109335-78-6
Mn₂(CO)8(diethylphenylphosphine)(triphenyl phosphite)

: 19568-52-6,105228-19-1
tetracarbonylhydrido(triphenyl phosphite)manganese

Guidance literature:: With tetrahydrofuran; In tetrahydrofuran; 5-mL aliquot of 1E-2 M Mn(CO)4P(OPh)3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5PPhEt2(1+) in THF at 22°C, react. complete within approx. 60 min; not isolated; detected by IR and TLC;
DOI:10.1021/om00152a010

Reference yield: 34.0%

: 71427-83-3
tetracarbonyl(triphenyl phosphite)manganate(-I) anion

: 54039-47-3
pentacarbonyl(dimethylphenylphosphine)manganese(I) cation

: 104419-63-8
tetracarbonylhydrido(dimethylphenylphosphine)manganese

: 55029-78-2
Mn₂(CO)8(dimethylphenylphosphine)2

: 15529-62-1,15228-70-3
Mn₂(CO)8(triphenyl phosphite)2

: 109335-81-1
Mn₂(CO)8(dimethylphenylphosphine)(triphenyl phosphite)

: 19568-52-6,105228-19-1
tetracarbonylhydrido(triphenyl phosphite)manganese

Guidance literature:: With tetrahydrofuran; In tetrahydrofuran; 5-mL aliquot of 1E-2 M Mn(CO)4P(OPh)3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5PPh2Me(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR and TLC;
DOI:10.1021/om00152a010